6-methyl-2-phenyl-5-(2-phenyl-3,6-dihydro-2H-[1,2]oxazin-6-yl)-3-p-tolyl-3H-pyrimidin-4-one | 1133712-09-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二嗪类
• 英文名称: 6-methyl-2-phenyl-5-(2-phenyl-3,6-dihydro-2H-[1,2]oxazin-6-yl)-3-p-tolyl-3H-pyrimidin-4-one
• CAS: 1133712-09-0
• 化学式: C₂₈H₂₅N₃O₂
• 分子量: 435.525
• InChiKey: FSEJRLGDBCGGOF-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  6-methyl-2-phenyl-5-(2-phenyl-3,6-dihydro-2H-[1,2]oxazin-6-yl)-3-p-tolyl-3H-pyrimidin-4-one 在 溶剂黄146 、 锌 作用下， 反应 1.0h， 以75%的产率得到5-(1-hydroxy-4-phenylamino-but-2-enyl)-6-methyl-2-phenyl-3-p-tolyl-3H-pyrimidin-4-one
  参考文献：
  名称：

  Regioselective Nitroso Diels-Alder Cycloaddition Reactions of 5-Dienylpyrimidinones and Transformation to Novel 4-Amino-Alcohol Tethered Pyrimidinones

  摘要：

  A highly regioselective nitroso Diets-Alder (NDA) cycloaddditon of nitroso benzene with variedly substituted 5-dienyl pyrimidinones with and the transformation of adducts to novel, unnatural, biologically important 4-amino alcohols is reported.

  DOI：

  10.3987/com-08-s(f)76
• 作为产物：
  描述：

  、 亚硝基苯 以 二氯甲烷 为溶剂， 反应 5.0h， 以82%的产率得到6-methyl-2-phenyl-5-(2-phenyl-3,6-dihydro-2H-[1,2]oxazin-6-yl)-3-p-tolyl-3H-pyrimidin-4-one
  参考文献：
  名称：

  Regioselective Nitroso Diels-Alder Cycloaddition Reactions of 5-Dienylpyrimidinones and Transformation to Novel 4-Amino-Alcohol Tethered Pyrimidinones

  摘要：

  A highly regioselective nitroso Diets-Alder (NDA) cycloaddditon of nitroso benzene with variedly substituted 5-dienyl pyrimidinones with and the transformation of adducts to novel, unnatural, biologically important 4-amino alcohols is reported.

  DOI：

  10.3987/com-08-s(f)76