N-benzoyl-N'-(p-hydroxythiobenzoyl)hydrazine | 748797-41-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N-benzoyl-N'-(p-hydroxythiobenzoyl)hydrazine
• 英文别名: N-nicotinoyl-N'-p-hydroxythiobenzhydrazine；N-benzoyl-N'-p-hydroxythiobenzhydrazine；H2Bptbh
• CAS: 748797-41-3
• 化学式: C₁₄H₁₂N₂O₂S
• 分子量: 272.327
• InChiKey: SKJFJTHGOWYCJH-UHFFFAOYSA-N

物化性质

• 熔点：
  126 °C
• 密度：
  1.332±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.0
• 重原子数：
  19.0
• 可旋转键数：
  2.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  61.36
• 氢给体数：
  3.0
• 氢受体数：
  3.0

反应信息

• 作为反应物：
  描述：

  cadmium(II) acetate dihydrate 、 N-benzoyl-N'-(p-hydroxythiobenzoyl)hydrazine 以 甲醇 、 乙醇 为溶剂， 以45%的产率得到[Cd(C6H4(OH)C(S)NNC(O)C6H5)]n
  参考文献：
  名称：

  Synthesis, Characterization, and Electrical Conductivities of Some Transition Metal Complexes of N‐Nicotinoyl‐N′‐p‐hydroxythiobenzhydrazine

  摘要：

  The complexes [m(L)](n), [M = VO(IV), Cu(II), Zn(II), Cd(II), Hg(II)] and [Fe(L)(acac)](n) with N-nicotinoyl-N'-p-hydroxythiobenzhydrazine (H2L) have been prepared and characterized by elemental analyses, magnetic susceptibility measurements, electronic, NMR (H-1 and C-13), IR and FAB mass spectral data. The physico-chemical studies indicate that the complexes are polymeric in nature. A square-pyramidal Structure for [VO(L)](n), an octahedral structure for [Fe(L)(acac)](n) and a square-planar structure for [Cu(L)], have been proposed. The Mossbauer spectra of [Fe(L)(acac)], at room temperature and at 78 K suggest the presence of high-spin (S = 5/2) octahedral Fe(III). The complexes of VO(IV), Fe(III) and Hg(II) show semiconducting behavoiour in the solid state in the temperature range 307-397 K, with a band gap of 0.44-1.32 eV. The other complexes are insulators.

  DOI：

  10.1081/sim-120023493
• 作为产物：
  描述：

  4-Hydroxy-dithiobenzoesaeure-(carboxy-methylester) 、 苯甲酰肼 在 sodium hydroxide 、 溶剂黄146 作用下， 反应 2.0h， 以80%的产率得到N-benzoyl-N'-(p-hydroxythiobenzoyl)hydrazine
  参考文献：
  名称：

  Singh; Kushawaha, Indian Journal of Chemistry, Section A: Inorganic, Physical, Theoretical and Analytical, 2004, vol. 43, # 2, p. 333 - 336

  摘要：

  DOI：