fac-tricyano[di(2-pyridylmethyl)amine]ferrate(III) | 158845-42-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯
• 英文名称: fac-tricyano[di(2-pyridylmethyl)amine]ferrate(III)
• CAS: 158845-42-2
• 化学式: C₁₅H₁₃FeN₆
• 分子量: 333.155
• InChiKey: ZIBDRHUPVIJPBX-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  sodium fac-tricyano[di(2-pyridylmethyl)amine]ferrate(II) 在 ammonium peroxydisulfate 作用下， 生成 fac-tricyano[di(2-pyridylmethyl)amine]ferrate(III)
  参考文献：
  名称：

  Dependence of dehydrogenation of amines towards coordination geometry: oxidation products of tricyano[di(2-pyridylmethyl)amine]ferrate(II) from mer and fac isomers

  摘要：

  Two geometrical isomers, mer- and fac-tricyano[di(2-pyridylmethyl)amine]ferrate(II) give the iron(II) complex with dehydrogenated ligand and iron(III) complex with intact ligand, respectively, upon oxidation with (NH4)2SO4 or H2O2 at neutral pH, which is confirmed by electrochemical measurements.

  DOI：

  10.1039/c39940002015