4,4'-二氨基-2,2'-二甲基联苄 | 22856-62-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 4,4'-二氨基-2,2'-二甲基联苄
• 英文名称: 1.1-Bis-<4-amino-2-methyl-phenyl>-ethan
• 英文别名: 4,4'-ethylenedi-m-toluidine；4,4'-ethylenedi-3-toluidine；4,4'-(Ethane-1,1-diyl)bis(3-methylaniline)；4-[1-(4-amino-2-methylphenyl)ethyl]-3-methylaniline
• CAS: 22856-62-8
• 化学式: C₁₆H₂₀N₂
• mdl: MFCD01104110
• 分子量: 240.348
• InChiKey: YIZBNZOKVQPEDO-UHFFFAOYSA-N

物化性质

• 熔点：
  170-173 °C(lit.)

计算性质

• 辛醇/水分配系数(LogP)：
  3.5
• 重原子数：
  18
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  52
• 氢给体数：
  2
• 氢受体数：
  2

安全信息

• 危险品标志：
  Xn
• 安全说明：
  S26,S37/39
• 危险类别码：
  R20/21/22,R36/37/38
• 海关编码：
  2921590090

反应信息

• 作为产物：
  描述：

  1-氯乙磺酰氯 、 3-甲基苯胺 以 苯 为溶剂， 生成 4,4'-二氨基-2,2'-二甲基联苄
  参考文献：
  名称：

  Kostsova,A.G. et al., Journal of Organic Chemistry USSR (English Translation), 1969, vol. 5, p. 508 - 510

  摘要：

  DOI：

文献信息

• NOVEL (POLY)AMINE COMPOUND, RESIN AND CURED PRODUCT
  申请人：Mitsubishi Gas Chemical Company, Inc.

  公开号：US20200172470A1

  公开（公告）日：2020-06-04

  A (poly)amine compound represented by the following formula (0): wherein R X is a 2n A -valent group having 1 to 70 carbon atoms or a single bond; each R 1A is independently any of an alkyl group having 1 to 30 carbon atoms and optionally having a substituent, an aryl group having 6 to 30 carbon atoms and optionally having a substituent, a crosslinking group having 2 to 30 carbon atoms and optionally having a substituent, an alkoxy group having 1 to 30 carbon atoms and optionally having a substituent, a halogen atom, a nitro group, an amino group having 0 to 30 carbon atoms and optionally having a substituent, a carboxyl group, a thiol group and a hydroxy group, wherein when R 1A is any of the alkyl group, the aryl group, the crosslinking group and the alkoxy group, R 1A optionally contains at least one bond selected from the group consisting of an ether bond, a ketone bond and an ester bond, and at least one R 1A is an amino group having 0 to 30 carbon atoms and optionally having a substituent; X is an oxygen atom or a sulfur atom, or X is optionally absent; each R independently represents any of a benzene ring, a biphenyl ring, a naphthalene ring, an anthracene ring and a pyrene ring; each m is independently an integer of 0 to 9, wherein at least one m is an integer of 1 to 9; and n A is an integer of 1 to 4.

  由以下公式（0）表示的（聚）胺化合物：其中RX是一个具有1到70个碳原子或单键的2nA价基团；每个R1A独立地是1到30个碳原子的烷基基团，可选地具有取代基，含有6到30个碳原子的芳基基团，可选地具有取代基，含有2到30个碳原子的交联基团，可选地具有取代基，含有1到30个碳原子的烷氧基团，可选地具有取代基，卤原子，硝基基团，含有0到30个碳原子的氨基基团，可选地具有取代基，羧基，硫醇基和羟基，其中当R1A是烷基基团、芳基基团、交联基团和烷氧基团中的任意一种时，R1A可选地含有至少一种从醚键、酮键和酯键组成的键，至少有一个R1A是含有0到30个碳原子且可选地具有取代基的氨基基团；X是氧原子或硫原子，或X可选地不存在；每个R独立地代表苯环、联苯环、萘环、蒽环和芘环中的任意一种；每个m独立地是0到9的整数，至少有一个m是1到9的整数；nA是1到4的整数。
• NOVEL (POLY)AMINE COMPOUND, RESIN, AND CURED PRODUCT
  申请人：Mitsubishi Gas Chemical Company, Inc.

  公开号：EP3659996A1

  公开（公告）日：2020-06-03

  A (poly)amine compound represented by the following formula (0): wherein RX is a 2nA-valent group having 1 to 70 carbon atoms or a single bond; each R1A is independently any of an alkyl group having 1 to 30 carbon atoms and optionally having a substituent, an aryl group having 6 to 30 carbon atoms and optionally having a substituent, a crosslinking group having 2 to 30 carbon atoms and optionally having a substituent, an alkoxy group having 1 to 30 carbon atoms and optionally having a substituent, a halogen atom, a nitro group, an amino group having 0 to 30 carbon atoms and optionally having a substituent, a carboxyl group, a thiol group and a hydroxy group, wherein when R1A is any of the alkyl group, the aryl group, the crosslinking group and the alkoxy group, R1A optionally contains at least one bond selected from the group consisting of an ether bond, a ketone bond and an ester bond, and at least one R1A is an amino group having 0 to 30 carbon atoms and optionally having a substituent; X is an oxygen atom or a sulfur atom, or X is optionally absent; each R independently represents any of a benzene ring, a biphenyl ring, a naphthalene ring, an anthracene ring and a pyrene ring; each m is independently an integer of 0 to 9, wherein at least one m is an integer of 1 to 9; and nA is an integer of 1 to 4.

  下式(0)代表的（多）胺化合物： 其中 RX 是具有 1 至 70 个碳原子的 2nA 价基团或单键； 每个 R1A 独立地是具有 1 至 30 个碳原子且任选具有一个取代基的烷基、具有 6 至 30 个碳原子且任选具有一个取代基的芳基、具有 2 至 30 个碳原子且任选具有一个取代基的交联基团、具有 1 至 30 个碳原子且任选具有一个取代基的烷氧基、卤素原子、硝基中的任一个、具有 0 至 30 个碳原子且可选择具有取代基的氨基、羧基、硫醇基和羟基，其中当 R1A 为烷基、芳基、交联基团和烷氧基中的任一个时，R1A 可选择包含至少一个选自由醚键、酮键和酯键组成的组中的键，且至少一个 R1A 为具有 0 至 30 个碳原子且可选择具有取代基的氨基； X 是氧原子或硫原子，或 X 可选择不存在； 每个 R 独立地代表苯环、联苯环、萘环、蒽环和芘环中的任一环； 每个 m 独立地为 0 至 9 的整数，其中至少一个 m 为 1 至 9 的整数；以及 nA 是 1 至 4 的整数。
• Kostsova,A.G. et al., Journal of Organic Chemistry USSR (English Translation), 1969, vol. 5, p. 508 - 510
  作者：Kostsova,A.G. et al.

  DOI：——

  日期：——