4,4'-二氨基-2,2'-二硝基二苯基甲烷 | 26946-33-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 4,4'-二氨基-2,2'-二硝基二苯基甲烷
• 英文名称: 4,4'-methylenebis(m-nitroaniline)
• 英文别名: 4,4'-diamino-2,2'-dinitrodiphenylmethane；bis-(4-amino-2-nitro-phenyl)-methane；Bis-(4-amino-2-nitro-phenyl)-methan；2.2'-Dinitro-4.4'-diamino-diphenylmethan；4,4'-methylenebis(3-nitro-benzenamine)；4,4'-methylenebis(3-nitroaniline)；4-[(4-amino-2-nitrophenyl)methyl]-3-nitroaniline
• CAS: 26946-33-8
• 化学式: C₁₃H₁₂N₄O₄
• 分子量: 288.263
• InChiKey: KENYTAOVAUETRB-UHFFFAOYSA-N

物化性质

• 熔点：
  202 °C
• 沸点：
  543.8±45.0 °C(Predicted)
• 密度：
  1.462±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.1
• 重原子数：
  21
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.08
• 拓扑面积：
  144
• 氢给体数：
  2
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  4,4'-二氨基-2,2'-二硝基二苯基甲烷 生成 3,3'-dinitro-4,4'-methanediyl-di-benzoic acid
  参考文献：
  名称：

  Duval, Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1908, vol. 146, p. 1325

  摘要：

  DOI：
• 作为产物：
  描述：

  4,4'-二氨基二苯甲烷 在 硫酸 、 potassium nitrate 作用下， 反应 3.0h， 生成 4,4'-二氨基-2,2'-二硝基二苯基甲烷
  参考文献：
  名称：

  Chiral polyesters with azobenzene moieties in the main chain, synthesis and evaluation of nonlinear optical properties

  摘要：

  报道了一系列新型手性共聚酯的合成、表征和非线性光学性质评估，这些共聚酯的主链含有推-拉电子偶氮苯介晶基团。这些共聚酯表现出液晶行为，具有较高的玻璃转变温度（约200°C）、稳定的液晶介相（高达360°C）以及较高的二次谐波生成（SHG）效率。二阶非线性电 susceptibilities 的值随着手性建筑单元的比例变化而测量，其时效稳定性在较长时间内表现显著。

  DOI：

  10.1039/a900567f

文献信息

• An adhesive system for bonding uncured rubber to cured polyurethane
  申请人：BRIDGESTONE/FIRESTONE, INC.

  公开号：EP0358084A2

  公开（公告）日：1990-03-14

  A thermosetting adhesive comprising a bis­maleimide compound and an isocyanate-terminated rubber polymer adapted to coreact upon heating is applied to substrate surfaces of a cured polyurethane and an uncured rubber compound. Upon heating, the adhesive crosslinks and the uncured rubber compound is preferably cured simultaneously. The adhesive is particularly useful in the fabrication of compositions by the bonding of cured polyurethane to an uncured rubber compound which becomes cured during the bonding process, such as in the con­struction of tires containing cured polyurethane rein­forcements within uncured rubber carcasses, the retread­ing of tires containing polyurethane repairs, etc.

  将一种由双马来酰亚胺化合物和异氰酸酯封端橡胶聚合物组成的热固性粘合剂涂抹在已固化聚氨酯和未固化橡胶复合物的基材表面，使其在加热时发生芯层反应。加热时，粘合剂交联，未固化的橡胶复合物最好同时固化。这种粘合剂特别适用于通过将固化聚氨酯粘合到未固化橡胶复合物（在粘合过程中变得固化）来制造组合物，例如在未固化橡胶胎体中含有固化聚氨酯补强材料的轮胎制造、含有聚氨酯修补材料的轮胎翻新等。
• Azo dimer and trimer fugitive tints
  申请人：MILLIKEN RESEARCH CORPORATION

  公开号：EP0498104A1

  公开（公告）日：1992-08-12

  Azo chromophores having polyoxyalkylene substituents are linked together by a covalent bond or by an intervening connecting group to form dimers or trimers. The polyoxyalkylene substituents are straight or branched chain polymers primarily of ethylene oxide which make the dimer and trimer colorants useful as fugitive tints.

  具有聚氧亚烷基取代基的偶氮发色团通过共价键或中间连接基团连接在一起，形成二聚体或三聚体。聚氧亚烷基取代基主要是环氧乙烷的直链或支链聚合物，这使得二聚体和三聚体着色剂可用作褪色剂。
• Colorants and intermediates therefor having branched poly(oxyalkylene)moieties, and their manufacture
  申请人：MILLIKEN RESEARCH CORPORATION

  公开号：EP0529162A1

  公开（公告）日：1993-03-03

  Colorants and compositions useful as a fugitive or permanent colorant for a variety of substrates, or as intermediates for their manufacture, and having one or more improved properties of enhanced aqueous washability, compatibility with and non-extractibility from thermoplastic resins, or reactivity with resins having reactive functionality, said composition having the formula C(Z)₁₋₈ wherein:    C is the residue of a reactant having from 1-8 nucleophilic site residues to which the Z moieties are attached; said Z moieties containing at least about 60 weight percent of poly(oxyalkylene) which is comprised of (a) at least one glycidol residue segment of 2-6 glycidol residues attached to a nucleophilic site of C, wherein said poly(oxyalkylene) contains a total of from 2-20 glycidol residues, (b) and wherein said poly(oxyalkylene) further contains the residues of one or more other epoxide reactants of ethylene oxide (EO), propylene oxide (PO), or butylene oxide (BO), or mixtures thereof, wherein said poly(oxyalkylene) contains a total of from about 10 to about 600 of said EO, PO or BO residues, or mixtures thereof, at least about 75 mole percent of which are EO residues, (c) and with the provisions that the ratio of the total of - O-PO- and -O-BO- linkages of all glycidol residues to the total of all functional oxy linkages of said glycidol residues is less than one, and the molar ratio of EO residues to glycidol residues is from 4 to 75.

  着色剂和组合物，可用作各种基材的褪色剂或永久性着色剂，或用作其制造的中间体，并具有一种或多种改进特性，即增强的水洗性、与热塑性树脂的相容性和不萃取性，或与具有反应官能团的树脂的反应性，所述组合物具有式 C(Z)₁₋₈ 其中，C 是反应物的残余物，反应物具有 1-8 个亲核部位残余物，Z 分子与反应物相连；所述 Z 分子含有至少约 60% 的聚(氧亚烷基)，该聚(氧亚烷基)是一种具有反应官能团的树脂： C 是反应物的残留物，该反应物具有 1-8 个亲核位点残留物，Z 分子附着在该残留物上；所述 Z 分子含有至少约 60 重量百分比的聚氧亚烷基，该聚氧亚烷基由以下物质组成 (a) 至少一个由 2-6 个缩水甘油残基组成的缩水甘油残基段，该段连接到 C 的亲核位点，其中所述聚（氧烷基）总共包含 2-20 个缩水甘油残基、 (b) 其中所述聚（氧烷基）进一步含有环氧乙烷（EO）、环氧丙烷（PO）或环氧丁 烷（BO）的一种或多种其它环氧化物反应物或其混合物的残基，其中所述聚（氧烷 基）总共含有约 10 至约 600 个所述环氧乙烷、环氧丙烷或环氧丁烷残基或其混 合物，其中至少约 75 摩尔％为环氧乙烷残基、 (c) 并规定所有缩水甘油残基的-O-PO-和-O-BO-链节总数与所述缩水甘油残基的所有官能氧链节总数之比小于1，且环氧乙烷残基与缩水甘油残基的摩尔比为4至75。
• MULTILAYER BODY COMPOSED OF FLUORORESIN LAYER AND ELASTOMER LAYER
  申请人：Daikin Industries, Ltd.

  公开号：EP2177353A1

  公开（公告）日：2010-04-21

  The present invention provides a laminated article having improved adhesion of the fluorine-containing resin layer to the elastomer layer. The laminated article comprises a fluorine-containing resin layer (a) formed using a fluorine-containing resin having a carbonyl group, an olefin group or an amino group at an end of a polymer trunk chain or an end of a polymer side chain, and an elastomer layer (b) formed using an elastomer composition.

  本发明提供了一种层压制品，其含氟树脂层与弹性体层的粘附性得到改善。层压制品包括含氟树脂层（a）和弹性体层（b），前者由在聚合物主链末端或聚合物侧链末端具有羰基、烯烃基或氨基的含氟树脂形成，后者由弹性体组合物形成。
• THERMOPLASTIC RESIN COMPOSITION AND METHOD FOR PRODUCING SAME
  申请人：DAIKIN INDUSTRIES, LTD.

  公开号：EP3760674A1

  公开（公告）日：2021-01-06

  The present invention provides a thermoplastic resin composition comprising a fluororesin (A) and a crosslinked fluoroelastomer (B), wherein the fluororesin (A) is a copolymer that contains a chlorotrifluoroethylene unit and a tetrafluoroethylene unit and that has at least one functional group selected from the group consisting of a carbonyl group, an olefinic group and an amino group at a main chain terminal or side chain terminal of the polymer, and wherein the crosslinked fluoroelastomer (B) is obtained by subjecting a fluoroelastomer (b) to a dynamic crosslinking treatment along with a polyamine compound (c) having a thermal decomposition temperature of 210°C or higher and a crosslinking accelerator (d) in the presence of the fluororesin (A) under conditions for melting the fluororesin (A).

  本发明提供了一种热塑性树脂组合物，该组合物包含氟树脂（A）和交联氟橡胶（B），其中氟树脂（A）是一种共聚物，它包含一个三氟氯乙烯单元和一个四氟乙烯单元，并且在聚合物的主链末端或侧链末端具有至少一个选自羰基、烯烃基和氨基的官能团、其中，交联氟弹性体（B）是在氟树脂（A）熔化的条件下，将氟弹性体（b）与热分解温度为 210℃或更高的多胺化合物（c）和交联促进剂（d）一起在氟树脂（A）存在下进行动态交联处理而得到的。