| 92382-60-0

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 酮酸及其衍生物
• CAS: 92382-60-0
• 化学式: C₆H₆Cl₂HgO₄
• 分子量: 413.607
• InChiKey: RBTJXTOZNYLHEI-UHFFFAOYSA-M

反应信息

• 作为反应物：
  描述：

  在 lithium tetrachloropalladate 作用下， 生成 1,2,3,4-Tetracarbomethoxy-1,4-dichlorbutadien-(1,3)
  参考文献：
  名称：

  Doebler,C. et al., Zeitschrift fur Chemie, 1971, vol. 11, p. 147 - 148

  摘要：

  DOI：
• 作为产物：
  描述：

  丁炔二酸二甲酯 在 水 、 mercury dichloride 作用下， 生成
  参考文献：
  名称：

  Nesmejanow et al., Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1950, p. 77,82

  摘要：

  DOI：

文献信息

• Metal-to-metal transfer of vinyl ligands: ruthenium-catalysed synthesis of vinylmercury compounds
  作者：Joseph R. Crook、Barbara Chamberlain、Roger J. Mawby、Fritjof C. F. Körber、Amanda J. Reid、Colin D. Reynolds

  DOI：10.1039/dt9920000843

  日期：——

  Vinyl ligands are readily transferred from ruthenium(II) to mercury(II), giving mono- or di-vinyl mercury complexes, depending on the vinyl ligand and the reaction conditions used. In conjunction with steps involving aryl ligand transfer from mercury to ruthenium and insertion of MeO2CC = CCO2Me into the ruthenium-aryl bond, this constitutes a ruthenium-catalysed route for the conversion of [HgR2] (R = aryl) into [HgC(CO2Me) = C(CO2Me)R}R] and [HgC(CO2Me) = C(CO2Me)R}2], with alkyne insertion as the rate-limiting step. The mechanism of transfer alters according to the nature of the vinyl ligand. Reaction of [Ru(CO)2C(CO2Me) = C(CO2Me)H}Cl(PMe2Ph)2] with HgCl2 does not lead to vinyl transfer: the product was characterized by X-ray crystallography as [activated Ru(CO)2C(CO2Me) = C(COOMe)H}-(PMe2Ph)2][HgCl3].