4,4'-联吡啶-2,2'-二羧酸 | 85531-49-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 中文名称: 4,4'-联吡啶-2,2'-二羧酸
• 中文别名: [4,4'-联吡啶]-2,2'-二甲酸
• 英文名称: 4,4'-bipyridine-2,2'-dicarboxylic acid
• 英文别名: [4,4']bipyridyl-2,2'-dicarboxylic acid；H2BPDCA；[4,4']Bipyridyl-2,2'-dicarbonsaeure；[4,4'-Bipyridine]-2,2'-dicarboxylic acid；4-(2-carboxypyridin-4-yl)pyridine-2-carboxylic acid
• CAS: 85531-49-3
• 化学式: C₁₂H₈N₂O₄
• 分子量: 244.207
• InChiKey: XHVUFVVPMVIQEY-UHFFFAOYSA-N

物化性质

• 沸点：
  558.9±50.0 °C(Predicted)
• 密度：
  1.469±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.1
• 重原子数：
  18
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  100
• 氢给体数：
  2
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  4,4'-联吡啶-2,2'-二羧酸 以64%的产率得到
  参考文献：
  名称：

  ZIYAEV, A. A.;XALILOVA, X. D.;MRDANOV, R. G.;TOLKACHEVA, G. A., SINTEZ I BIOL. AKTIVNOST ORGAN. SOED., TASHKENT, 1985, 67-71

  摘要：

  DOI：
• 作为产物：
  描述：

  alkaline earth salt of/the/ methylsulfuric acid 在 potassium permanganate 作用下， 生成 4,4'-联吡啶-2,2'-二羧酸
  参考文献：
  名称：

  Heuser; Stoehr, Journal fur praktische Chemie (Leipzig 1954), 1891, vol. <2> 44, p. 407

  摘要：

  DOI：

文献信息

• Luminescent metal-ligand complexes
  申请人：LJL BioSystems, Inc.

  公开号：US20010021514A1

  公开（公告）日：2001-09-13

  Luminescent metal-ligand complexes and/or complementary energy transfer acceptors for use in luminescence assays. The complexes and/or acceptors may be used in free, reactive, and/or conjugated form, alone or mixed with other compounds. Preferred luminescence assays include luminescence polarization and luminescence resonance energy transfer assays, among others.

  荧光金属配合物和/或互补能量转移受体用于荧光测定。这些配合物和/或受体可以以自由、反应性和/或共轭形式使用，单独或与其他化合物混合使用。首选的荧光测定包括荧光偏振和荧光共振能量转移测定，等等。
• Unprecedented cadmium(II) complex with (44·66) net topology and in situ ligand synthesis
  作者：Zheng-Shuai Bai、Jing Xu、Zhi Su、Wei-Yin Sun

  DOI：10.1016/j.inoche.2008.07.019

  日期：2008.10

  Hydrothermal reactions of 4,4'-bipyridine-2,2'-dicarboxylic acid (H(2)BPDCA) with Cu(II) and Cd(II) nitrate salts result in the formation of two complexes [Cu(2,4-Hpydca)(2)(H2O)(2)] (1) and [Cd(2,4-pydca)](n) (2) with pyridine-2,4-dicarboxylate (2,4-pydca(2-)), rather than BPDCA(2-), as ligand, namely the in situ transformation of H(2)BPDCA to H(2)pydca occurred under the hydrothermal conditions. Complex 1 has been previously reported from different synthetic route, however, complex 2 is the first binodal 5-connecting 3D frame-work with unprecedented (4(4) . 6(6)) net topology. The results provide a new strategy for in situ ligand synthesis and construction of coordination polymers with specific topology. (C) 2008 Elsevier B.V. All rights reserved.
• [EN] LUMINESCENT METAL-LIGAND COMPLEXES<br/>[FR] COMPLEXES METAL-LIGAND LUMINESCENTS
  申请人：LJL BIOSYSTEMS INC

  公开号：WO2000047693A1

  公开（公告）日：2000-08-17

  Luminescent metal-ligand complexes and/or complementary energy trnsfer acceptors for use in luminescence assays. The complexes and/or acceptors may be use in free, reactive, and/or conjugated form, alone or mixed with other compounds. Preferred luminescence assays include luminescence polarization and luminescence resonance energy transfer assays, among others.