{RuCl2(3-CH3-C5H4N)4} | 16997-44-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: {RuCl2(3-CH3-C5H4N)4}
• 英文别名: trans-{RuCl2(3-CH3-C5H4N)4}；[RuCl2(β-pic)4]；[RuCl2(β-picoline)4]
• CAS: 16997-44-7；207620-94-8；866487-58-3
• 化学式: C₂₄H₂₈Cl₂N₄Ru
• 分子量: 544.489
• InChiKey: RNEXKDJQWNWDTJ-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  {RuCl2(3-CH3-C5H4N)4} 、 硝酸 以 硝酸 为溶剂， 生成
  参考文献：
  名称：

  Souchek, J., Collection of Czechoslovak Chemical Communications, 1962, vol. 27, p. 1645 - 1650

  摘要：

  DOI：
• 作为产物：
  描述：

  3-甲基吡啶 在 NH₄ chlororuthenate(III) 作用下， 以 neat (no solvent) 为溶剂， 生成 {RuCl2(3-CH3-C5H4N)4}
  参考文献：
  名称：

  Lewis, J.; Mabbs, F. E.; Walton, R. A., Journal of the Chemical Society A: Inorganic, Physical, Theoretical, 1967, p. 1366 - 1370

  摘要：

  DOI：

文献信息

• One-pot and selective synthesis of a series of [RuCl6−2nLn] (L=bidentate ligand, n=0−3) types of complexes with polypyridyl ligands; another example of the synthetic utility of ‘ruthenium-blue’ solution
  作者：Tadashi Togano、Noriharu Nagao、Mitsuko Tsuchida、Hiromi Kumakura、Kumiko Hisamatsu、F.Scott Howell、Masao Mukaida

  DOI：10.1016/s0020-1693(00)85316-5

  日期：1992.5

  Convenient (one-pot) and selective syntheses of a series of ruthenium complexes with polypyridyl ligands, [RuL3]2+, cis-[RuCl2L2]+ and [RuCl4L]- (L=bpy, phen or Hdpa (di-2,2-dipyridylamine)), including [RuCl6]3-, have been reported as further examples of the synthetic utility of 'ruthenium-blue' solution. The methods developed here are also useful for synthesizing selectively such pair complexes as [Ru(III)Cl3(terpy)]-[Ru(II)(terpy)2]2+ and [Ru-(III)Cl4py2]--[Ru(II)Cl2py4].
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Ru: SVol., 139, page 394 - 396
  作者：

  DOI：——

  日期：——
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Ru: SVol., 168, page 456 - 458
  作者：

  DOI：——

  日期：——
• Synthesis and characterization of [RuCl2(picoline)4] complexes: Crystal structure of [RuCl2(β-pic)4]
  作者：J.G. Małecki、M. Jaworska、R. Kruszynski、R. Gil-bortnowska

  DOI：10.1016/j.poly.2005.03.092

  日期：2005.8

  The reaction of the [RuCl2(PPh3)(3)] complex with picolines has been examined. New ruthenium(II) complexes - [RuCl2(C6H7N)(4)] have been obtained and characterized by IR, H-1 NMR and UV-Vis measurements. The crystal structure of the [RuCl2(beta-pic)(4)] complex has been determined. The electronic spectra of the complexes have been calculated by the TDDFT method. (c) 2005 Elsevier Ltd. All rights reserved.