| 191988-23-5

• 分子结构分类: 有机化合物 - 有机氧化合物 - 有机含氧阴离子化合物
• CAS: 191988-23-5
• 化学式: C₁₇H₃₆N₈O₄Rh
• 分子量: 519.43
• InChiKey: OAHSSGXMAHCUKP-OKZTUQRJSA-N

反应信息

• 作为反应物：
  描述：

  在 HCl 、 Sn 作用下， 以 not given 为溶剂， 生成
  参考文献：
  名称：

  The influence of cavity size on the properties of encapsulated rhodium(III) lons: long-lived metal-centred emission in a symmetric expanded cavity rhodium cage system

  摘要：

  Efficient and rapid metal template reactions of rhodium(III) hexaamine complexes with paraformaldehyde and nitromethane under non-aqueous conditions lead to both optimal and expanded cavity cage complexes with widely differing X-ray structures and electronic properties; the larger cavity homologues feature a strongly enhanced metal-centred phosphorescence in water at 77 K.

  DOI：

  10.1039/c39940000667
• 作为产物：
  描述：

  硝基甲烷 、 、 {rhodium tris(1,3-propanediamine)} trifluoromethanesulfonate 在 triethyl amine 、 acetic acid 作用下， 以 乙腈 为溶剂， 生成
  参考文献：
  名称：

  The influence of cavity size on the properties of encapsulated rhodium(III) lons: long-lived metal-centred emission in a symmetric expanded cavity rhodium cage system

  摘要：

  Efficient and rapid metal template reactions of rhodium(III) hexaamine complexes with paraformaldehyde and nitromethane under non-aqueous conditions lead to both optimal and expanded cavity cage complexes with widely differing X-ray structures and electronic properties; the larger cavity homologues feature a strongly enhanced metal-centred phosphorescence in water at 77 K.

  DOI：

  10.1039/c39940000667