(1S,2R,5S,6R)-9-Oxo-tricyclo[4.2.1.0^2,5]nona-3,7-diene-3,4-dicarboxylic acid dimethyl ester | 160815-00-9

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: (1S,2R,5S,6R)-9-Oxo-tricyclo[4.2.1.0^2,5]nona-3,7-diene-3,4-dicarboxylic acid dimethyl ester
• CAS: 160815-00-9
• 化学式: C₁₃H₁₂O₅
• 分子量: 248.235
• InChiKey: DCFSITBOZLEMBG-KVFPUHGPSA-N

物化性质

• 沸点：
  385.709±42.00 °C(Press: 760.00 Torr)(predicted)
• 密度：
  1.410±0.06 g/cm3(Temp: 25 °C; Press: 760 Torr)(predicted)

反应信息

• 作为反应物：
  描述：

  丁炔二酸二甲酯 、 (1S,2R,5S,6R)-9-Oxo-tricyclo[4.2.1.0^2,5]nona-3,7-diene-3,4-dicarboxylic acid dimethyl ester 在 RuH₂CO(PAr₃)3 Ar=aryl 作用下， 生成
  参考文献：
  名称：

  Homoladderanes: A Chevron-shaped motif for molecular design

  摘要：

  Serial application of Ruthenium-catalysed [2 pi+2 pi] cycloaddition of DMAD followed by cyclobutadiene [4 pi+2 pi] cycloaddition is used to construct ladderanes incorporating a central norbornane. The resultant homoladderanes are chevron shaped spacer-units in which the apical angle can be varied by modification of the central methylene bridge of the norbornane unit. Synthesis of 11-oxa and 11-keto tetracyclo[4.4.1.0(2,5).0(7,6)] undeca-3,8-dien-3,4,8,9-tetraesters is reported as prototype central units for homoladderane construction.

  DOI：

  10.1016/s0040-4039(00)78363-8
• 作为产物：
  描述：

  (1S,2R,5S,6R)-9-Hydroxy-tricyclo[4.2.1.0^2,5]nona-3,7-diene-3,4-dicarboxylic acid dimethyl ester 在 Swern oxidation reagents 作用下， 生成 (1S,2R,5S,6R)-9-Oxo-tricyclo[4.2.1.0^2,5]nona-3,7-diene-3,4-dicarboxylic acid dimethyl ester
  参考文献：
  名称：

  Homoladderanes: A Chevron-shaped motif for molecular design

  摘要：

  Serial application of Ruthenium-catalysed [2 pi+2 pi] cycloaddition of DMAD followed by cyclobutadiene [4 pi+2 pi] cycloaddition is used to construct ladderanes incorporating a central norbornane. The resultant homoladderanes are chevron shaped spacer-units in which the apical angle can be varied by modification of the central methylene bridge of the norbornane unit. Synthesis of 11-oxa and 11-keto tetracyclo[4.4.1.0(2,5).0(7,6)] undeca-3,8-dien-3,4,8,9-tetraesters is reported as prototype central units for homoladderane construction.

  DOI：

  10.1016/s0040-4039(00)78363-8