3-Hexadecoxycarbonyloxirane-2-carboxylic acid | 1192236-01-3

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: 3-Hexadecoxycarbonyloxirane-2-carboxylic acid
• CAS: 1192236-01-3
• 化学式: C₂₀H₃₆O₅
• 分子量: 356.503
• InChiKey: ZKIQMKVXTDVBOD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.2
• 重原子数：
  25
• 可旋转键数：
  18
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.9
• 拓扑面积：
  76.1
• 氢给体数：
  1
• 氢受体数：
  5

反应信息

• 作为产物：
  描述：

  1-十六烷醇 在 [ϖ-C5H5N(CH2)15CH3]3PO4(WO3)4 、 双氧水 作用下， 以 水 为溶剂， 反应 6.0h， 生成 3-Hexadecoxycarbonyloxirane-2-carboxylic acid
  参考文献：
  名称：

  Epoxidation of Monomaleate with Hydrogen Peroxide Catalyzed by [π-C₅H₅N(CH₂)₁₅CH₃]₃PO₄(WO₃)₄

  摘要：

  In the study, epoxidation of dodecanol monomaleate, hexadecanol monomaleate, and octadecanol monomaleate were carried out using [pi-C5H5N(CH2)(15)CH3](3)PO4(WO3)(4) as phase-transfer catalyst with 30% hydrogen peroxide as oxidant. The experimental results showed that [pi-C5H5N(CH2)(15)CH3](3)PO4(WO3)(4) had excellent catalytic effect on translating C-C double-bond into an epoxy group and had a good yield rate. The synthesized epoxides of decanol monomaleate, hexadecanol monomaleate, and octadecanol monomaleate have enormous potential application in organic synthesis, and they could be readily transformed into various synthetically useful intermediates or final products in many fields of chemistry.

  DOI：

  10.1080/00397911.2010.518277

文献信息

• Epoxidation of Monomaleate with Hydrogen Peroxide Catalyzed by [π-C₅H₅N(CH₂)₁₅CH₃]₃PO₄(WO₃)₄
  作者：Zhiliang Zhang、Tianduo Li

  DOI：10.1080/00397911.2010.518277

  日期：2011.11.15

  In the study, epoxidation of dodecanol monomaleate, hexadecanol monomaleate, and octadecanol monomaleate were carried out using [pi-C5H5N(CH2)(15)CH3](3)PO4(WO3)(4) as phase-transfer catalyst with 30% hydrogen peroxide as oxidant. The experimental results showed that [pi-C5H5N(CH2)(15)CH3](3)PO4(WO3)(4) had excellent catalytic effect on translating C-C double-bond into an epoxy group and had a good yield rate. The synthesized epoxides of decanol monomaleate, hexadecanol monomaleate, and octadecanol monomaleate have enormous potential application in organic synthesis, and they could be readily transformed into various synthetically useful intermediates or final products in many fields of chemistry.