N,N'-Diphenyl-p,p'-diphenochinonimin | 99328-86-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N,N'-Diphenyl-p,p'-diphenochinonimin
• 英文别名: diquinonediimine；[3,3']bicyclohexa-1,4-dienylidene-6,6'-dione-bis-phenylimine；[3,3']Bicyclohexa-1,4-dienyliden-6,6'-dion-bis-phenylimin；Diphenochinon-(4.4')-bis-phenylimin；Diphenochinon-(4.4')-dianil
• CAS: 99328-86-6
• 化学式: C₂₄H₁₈N₂
• 分子量: 334.42
• InChiKey: FGGKKHPUGALWGH-VODLFZFFSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.08
• 重原子数：
  26.0
• 可旋转键数：
  2.0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  24.72
• 氢给体数：
  0.0
• 氢受体数：
  2.0

反应信息

• 作为产物：
  描述：

  N,N'-二苯基联苯二胺 在 sodium dichromate 、 硫酸 、 溶剂黄146 作用下， 生成 N,N'-Diphenyl-p,p'-diphenochinonimin
  参考文献：
  名称：

  Kehrmann; Micewitz, Chemische Berichte, 1912, vol. 45, p. 2651

  摘要：

  DOI：

文献信息

• Kinetics and mechanism of the oxidation of diphenylamine by Tc(VII) catalyzed by the Cu(II) ion
  作者：F. Grases、E. Amat、J. Palou

  DOI：10.1016/0304-5102(87)80095-0

  日期：1987.6

  pertechnetate ion oxidizes diphenylamine in the presence of the Cu(II) ion in acid media, to form a blue-violet diquinonediimine. This process was investigated and a reaction mechanism has been developed in accordance with the experimental data found. The results of this study support the hypothesis that the catalyst action is due to the ability of the Cu(II) ion to bind with diphenylamine. The Arrhenius parameter

  高tech酸根离子在酸性介质中在Cu（II）离子存在下将二苯胺氧化，从而形成蓝紫色的二醌二亚胺。对这一过程进行了研究，并根据发现的实验数据开发了反应机理。这项研究的结果支持以下假设：催化剂的作用是由于Cu（II）离子与二苯胺结合的能力。还对Arrhenius参数进行了研究。
• Kehrmann; Micewicz, Chemische Berichte, 1912, vol. 45, p. 2647
  作者：Kehrmann、Micewicz

  DOI：——

  日期：——
• Laughing Their Heads Off: Nineteenth–Century Comic Versions of the Bluebeard Tale
  作者：Mererid Puw Davies

  DOI：10.1111/1468-0483.00233

  日期：2002.10

  The Blaubartmärchen rewards study because it encodes key notions about gender, order, and the nature of fairy tale. In contrast to comic French and English traditions, the canonical German Blaubartmärchen is serious and tragic. However, a rich, forgotten nineteenth–century tradition of popular German Bluebeard comedies exists.Franz von Pocci’s Kasperliade (1859) seems to promote conservative authority structures but subtextually evokes carnivalesque subversion. Alexander von Sternberg’s Märchen (1850) involves transgressive gender roles, indeed an (albeit very limited) deconstruction of gender, before resorting to defensive reinscription of conservative gender roles. F.W. Hackländer’s realist novella (1863) seems to lack subversive moments in its denial that Bluebeard is evil, but a closer reading shows up its uneasy moments; and Roderich Benedix’s play (1861) is unique in challenging the Märchen plot and established gender roles.Laughter here restores order and ridicules characters who transgress; but it is also used in complex ways as an inoculation against fear. Despite seeming to share cultural and political values with texts in the canon, these comedies are nonetheless excluded because they deviate formally from the Grimmian Märchen and question the canonical view that Märchen must be ancient and serious. Given that these texts were more popular than the Grimms’, a review of notions of the Märchen, folk and popular culture is required. Some of the texts also undermine canonical values in dangerous ways by using laughter to rob Bluebeard of his terror and power.
• Deriaz et al., Journal of the Chemical Society, 1949, p. 1222,1227,1231
  作者：Deriaz et al.

  DOI：——

  日期：——
• PROPERTIES OF DIPHENYLAMINE AND DIPHENYLBENZIDINE AS OXIDATION-REDUCTION INDICATORS
  作者：I. M. Kolthoff、L. A. Sarver

  DOI：10.1021/ja01374a001

  日期：1930.11