[Co2(2,7,13,18-tetramethyl-3,6,14,17-tetraazatricyclo-[17.3.1.1]tetracosa-1(23)2,6,8(24),8,11,13,17,19,21-decaene-9,11,20,22-tetraol(4-))] | 1180664-67-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯
• 英文名称: [Co2(2,7,13,18-tetramethyl-3,6,14,17-tetraazatricyclo-[17.3.1.1]tetracosa-1(23)2,6,8(24),8,11,13,17,19,21-decaene-9,11,20,22-tetraol(4-))]
• CAS: 1180664-67-8
• 化学式: C₂₄H₂₄Co₂N₄O₄
• 分子量: 550.465
• InChiKey: QAIPJZVDWODKLC-BRDVPPHLSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  2,7,13,18-tetramethyl-3,6,14,17-tetraazatricyclo-[17.3.1.1]tetracosa-1(23)2,6,8(24),8,11,13,17,19,21-decaene-9,11,20,22-tetraol 、 cobalt(II) diacetate tetrahydrate 在 (C₂H₅)3N 作用下， 以 甲醇 为溶剂， 生成 [Co2(2,7,13,18-tetramethyl-3,6,14,17-tetraazatricyclo-[17.3.1.1]tetracosa-1(23)2,6,8(24),8,11,13,17,19,21-decaene-9,11,20,22-tetraol(4-))]
  参考文献：
  名称：

  Synthesis, characterization and catalytic oxidation of cyclohexane using a novel host (zeolite-Y)/guest (binuclear transition metal complexes) nanocomposite materials

  摘要：

  Transition metal (M = Mn(II), Co(II), Ni(II) and Cu(II)) complexes with octahydro-Schiff base (H-4-N4O4) = 2,7,13,18-tetramethyl-3,6,14,17-tetraazatricyclo-[17.3.1.1]-tetracosa-1(23), 2,6,8(24), 9,11,13,17,19,21-decaene-9,11,20,22-tetraol; H-4([H](8)-N4O4) = 2,7,13,, 18-tetramethyl-3,6,14,17-tetraazatricyclo-[17.13.1. 1.]-tetracosa-1(23), 8(24), 9,11,19,21-hexane-9,11,20,22-tetraol) have been encapsulated in nanopores of zeolite-Y; [M([H](8)-N4O4)]@NaY; with Flexible Ligand Method (FLM) for the first time. The new Host-Guest Nanocomposite Materials (HGNM) was characterized by several techniques: chemical analysis, spectroscopic methods (DRS, FT-IR and UV/Vis), BET technique, conductometric and magnetic measurements. The catalytic activities for oxidation of cyclohexane with HGNM complexes are reported. Zeolite encapsulated octahydro-Schiff base copper(II) complex; [Cu([H](8)-N4O4)]@NaY; was found to be more active than the corresponding cobalt(II), manganese(II) and nickel(II) complexes for cyclohexane oxidation. The catalytic properties of the complexes are influenced by their geometry and by the steric environment of the active sites. HGNM are stable enough to be reused and are suitable to be utilized as partial oxidation catalysts. The encapsulated catalysts systems; [M([H](8)-N4O4)]@NaY; were more active than the corresponding neat complexes; [M([H](8)-N4O4)))]. (C) 2009 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.ica.2009.04.028