α-Chlor-propionsaeure-vinylester | 88417-56-5

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: α-Chlor-propionsaeure-vinylester
• 英文别名: Ethenyl 2-chloropropanoate
• CAS: 88417-56-5
• 化学式: C₅H₇ClO₂
• 分子量: 134.562
• InChiKey: BTOIAAYVFNXNPA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.6
• 重原子数：
  8
• 可旋转键数：
  3
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

文献信息

• NOVEL DIARYLAMINE COMPOUNDS, AGING INHIBITOR, POLYMER COMPOSITION, CROSSLINKED RUBBER PRODUCT AND MOLDED ARTICLE OF THE CROSSLINKED PRODUCT, AND METHOD OF PRODUCING DIARYLAMINE COMPOUND
  申请人：Sakamoto Kei

  公开号：US20120101196A1

  公开（公告）日：2012-04-26

  There are provided a novel diarylamine compound represented by the following formula (I), (II) or (III), which has at least one signal attributable to the hydrogen of the N—H moiety at 8.30 ppm to 9.00 ppm when a deuterated dimethyl sulfoxide solution of the diarylamine compound is analyzed by 1 H-NMR; and an aging inhibitor, a polymer composition, a crosslinked rubber product and a molded article thereof, and a method of producing a diarylamine compound. In the formulas, A 1 to A 6 each represent an aromatic group which may have a substituent; A represents an aromatic group or a cyclic aliphatic group, which may both have a substituent; L represents 1 or 2; and n represents 0 or 1.

  提供了一种新型的二芳基胺化合物，其由以下公式（I）、（II）或（III）表示，当通过1H-NMR分析二芳基胺化合物的氘代二甲基亚磺酸溶液时，具有至少一种可归因于N-H基团的氢的信号在8.30 ppm至9.00 ppm之间；以及一种抗老化剂、一种聚合物组合物、一种交联橡胶产品及其模压制品，以及一种生产二芳基胺化合物的方法。在公式中，A1到A6分别表示可能具有取代基的芳香族基；A表示芳香族基或环状脂肪族基，两者都可能具有取代基；L表示1或2；n表示0或1。
• PROCESSING AID COMPOSITION DERIVED FROM A SULFINATE-CONTAINING MOLECULE
  申请人：3M INNOVATIVE PROPERTIES COMPANY

  公开号：US20140378594A1

  公开（公告）日：2014-12-25

  Described herein is a melt-processible polymer composition comprising: a non-fluorinated melt-processible polymer; and a fluoropolymer derived from the polymerization of a monomer and a sulfinate-containing molecule, wherein the sulfinate-containing molecule is selected from the group consisting of: (a) CX 1 X 3 ═CX 2 —(R) p —CZ 1 Z 2 —SO 2 M Formula (I) (b) Formula (II); and (c) combinations thereof, wherein X 1 , X 2 , and X 3 are each independently selected from H, F, Cl, a C 1 to C 4 alkyl group, and a C 1 to C 4 fluorinated alkyl group; R is a linking group; Z 1 and Z 2 are independently selected from F, CF 3 , and a perfluoroalkyl group; R 1 and R 2 are end-groups; p is 0 or 1; m is at least 2; and M is a cation.

  本文描述了一种可熔处理的聚合物组合物，包括：一种非氟可熔处理聚合物；以及由单体和含有磺酸盐分子聚合而成的氟聚合物，其中所述的磺酸盐分子选自以下组：（a）CX1X3═CX2—（R）p—CZ1Z2—SO2M式（I）；（b）式（II）；和（c）其组合物，其中X1、X2和X3各自独立选择自H、F、Cl、C1到C4烷基和C1到C4氟烷基；R是连结基；Z1和Z2各自独立选择自F、CF3和全氟烷基；R1和R2是末端基；p为0或1；m至少为2；M是阳离子。
• FLUORINE-CONTAINING POLYMER COMPOSITION
  申请人：3M INNOVATIVE PROPERTIES COMPANY

  公开号：US20160032087A1

  公开（公告）日：2016-02-04

  Described herein is a melt-processible polymer composition comprising: a non-fluorinated melt-processible polymer; and a fluorine-containing polymer comprising an end-group having a structures from group consisting of: and combinations thereof; wherein X 1 , X 2 , and X 3 are each independently selected from H, F, Cl, a C 1 to C 4 alkyl group, and a C 1 to C 4 fluorinated alkyl group; R 7 is a linking group comprising at least 2 or more catenary atoms; and Z 1 and Z 2 are independently selected from F, CF 3 , and a perfluoroalkyl group.

  这里描述了一种可熔性聚合物组合物，包括：一种非氟化可熔性聚合物；以及一种含氟聚合物，该聚合物包括具有以下结构的末端基团组合：其中X1、X2和X3各自独立地选自H、F、Cl、C1到C4烷基和C1到C4氟烷基；R7是至少包含2个或更多链原子的连接基团；Z1和Z2各自独立地选自F、CF3和全氟烷基。
• Blends of polyolefin graft polymers and ASA polymers, SMA polymers and condensation polymers
  申请人：OCCIDENTAL CHEMICAL CORPORATION

  公开号：EP0137518A2

  公开（公告）日：1985-04-17

  A novel thermoplastic polymer composition comprises a blend of (A) a polyolefin graft polymer and (B) a copolymer of acrylonitrile and styrene modified with a base polymer such as an acrylic polymer, a chlorinated polyethylene, or a terpolymer of styrene, acrylonitrile and a polyene modifier, or (C) a copolymer of styrene and maleic anhydride and modifications thereof, or (D) a condensation polymer such as a polycarbonate, a polyester of bisphenol and phthalic acids, or a polyalkylene terephthalate.

  一种新型热塑性聚合物组合物包括以下物质的混合物：(A)聚烯烃接枝聚合物；(B)丙烯腈和苯乙烯的共聚物，该共聚物用丙烯酸聚合物、氯化聚乙烯或苯乙烯的三元共聚物等基础聚合物改性，或(C)苯乙烯和马来酸酐的共聚物及其改性物；或(D)聚碳酸酯等缩聚聚合物、(C) 苯乙烯和马来酸酐的共聚物及其改性物，或 (D) 缩合聚合物，如聚碳酸酯、双酚和邻苯二甲酸的聚酯或聚对苯二甲酸乙二醇酯。
• Graft polymers of polymerizable monomers and olefin polymers
  申请人：OCCIDENTAL CHEMICAL CORPORATION

  公开号：EP0137519A2

  公开（公告）日：1985-04-17

  Graft polymers are prepared by reacting an ethylenically unsaturated polymerizable monomer with a polymer of an olefin of 2 to about 8 carbon atoms in a process wherein the olefin polymer is substantially insoluble in the monomer but is capable of absorbing the monomer. In a preferred aspect, a vinyl halide polyolefin graft polymer is produced by reacting a solid polyolefin particle with a vinyl halide monomer in which the polyolefin is substantially insoluble, but is capable of absorbing the monomer. The solid particles can be contacted with the monomer in one step or in stages. When the stage-wise reaction is continued until the proportion of polyolefin in the polymer product is about 2 to about 20 weight percent, the resulting product can be formed to a transparent or translucent article. When a small proportion of solid polyolefin is employed in the polymerization process, both a graft polymer and a polymer of the unsaturated monomer are simultaneously produced in the same reactor and can be readily mechanically separated into the individual products.

  接枝聚合物是通过乙烯基不饱和可聚合单体与 2 至 8 个碳原子的烯烃聚合物反应制备的，反应过程中烯烃聚合物基本上不溶于单体，但能吸收单体。在一个优选方面，卤化乙烯基聚烯烃接枝聚合物是通过固体聚烯烃颗粒与卤化乙烯基单体反应制得的，其中聚烯烃基本上不溶于卤化乙烯基单体，但能吸收单体。固体颗粒可以一步或分阶段与单体接触。当分阶段反应持续进行，直到聚合物产品中聚烯烃的比例达到约 2% 至约 20% 的重量百分比时，所得产品可形成透明或半透明制品。当在聚合过程中使用小比例的固体聚烯烃时，接枝聚合物和不饱和单体聚合物可在同一反应器中同时生产，并能很容易地机械分离成单个产品。