| 912477-23-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 恶嗪烷类
• CAS: 912477-23-7
• 化学式: C₁₁H₁₉BiN₂O₂S₄
• 分子量: 548.528
• InChiKey: DMSGXKNWSONMRJ-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  以 xylene 为溶剂， 生成 bismuth(III) sulfide
  参考文献：
  名称：

  Synthesis and characterization of methylbismuth(III) complexes containing dithio ligands: 2. Crystal and molecular structure of [MeBiCl(S2CNEt2)] and transformation of some to Bi2S3

  摘要：

  Reactions of methylbismuth(III) dichloride with sodium salts of dithiocarbmates have been carried out in 1: 1 and 1:2 stoichiometric ratios in anhydrous benzene to yield products of the types [MeBiCl(S2CNR2)] [where R = Me (1), Et (2) and Pr-i (3)] and[GRAPHICS]These complexes were characterized by elemental analyses and by FT-IR and NMR (H-1 and C-13) spectra. The X-ray structure of [MeBiCl(S2CNEt2)](2), indicates the presence of unique (BiClBi)-Cl-...-Bi-... secondary bonds resulting in a distorted square pyramidal environment around the central bismuth(III) atom. TGA of (6) shows a single step break down of the complex to Bi2S3 at 262.8 degrees C. Transformations of (6) and (8) to pure Bi2S3 have been carried out successfully in refluxing xylene (142 degrees C) as revealed by XRD and SEM studies. (c) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2006.06.023
• 作为产物：
  描述：

  sodium N-morpholinocarbamodithioate 、 Methylwismutdichlorid 以 苯 为溶剂， 以68%的产率得到
  参考文献：
  名称：

  Synthesis and characterization of methylbismuth(III) complexes containing dithio ligands: 2. Crystal and molecular structure of [MeBiCl(S2CNEt2)] and transformation of some to Bi2S3

  摘要：

  Reactions of methylbismuth(III) dichloride with sodium salts of dithiocarbmates have been carried out in 1: 1 and 1:2 stoichiometric ratios in anhydrous benzene to yield products of the types [MeBiCl(S2CNR2)] [where R = Me (1), Et (2) and Pr-i (3)] and[GRAPHICS]These complexes were characterized by elemental analyses and by FT-IR and NMR (H-1 and C-13) spectra. The X-ray structure of [MeBiCl(S2CNEt2)](2), indicates the presence of unique (BiClBi)-Cl-...-Bi-... secondary bonds resulting in a distorted square pyramidal environment around the central bismuth(III) atom. TGA of (6) shows a single step break down of the complex to Bi2S3 at 262.8 degrees C. Transformations of (6) and (8) to pure Bi2S3 have been carried out successfully in refluxing xylene (142 degrees C) as revealed by XRD and SEM studies. (c) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2006.06.023