6,6,6-Trifluorohexylmercaptan | 914642-05-0

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫醇
• 英文名称: 6,6,6-Trifluorohexylmercaptan
• 英文别名: 6,6,6-trifluorohexane-1-thiol
• CAS: 914642-05-0
• 化学式: C₆H₁₁F₃S
• 分子量: 172.21
• InChiKey: VGKLEAKHGYTALD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.6
• 重原子数：
  10
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  1
• 氢给体数：
  1
• 氢受体数：
  4

文献信息

• AROMATIC COMPOUND AND USE THEREOF
  申请人：SUMITOMO CHEMICAL COMPANY, LIMITED

  公开号：US20160311775A1

  公开（公告）日：2016-10-27

  An aromatic compound represented by formula (1): wherein R 1 and R 2 each independently represents a halogen atom, a C1-C4 alkyl group, or a C1-C4 haloalkyl group; m and n each independently represents an integer of 0 to 4; R 3 and R 4 each represents a hydrogen atom; Y represents formula: —OC(═X)ZR 5 or —SC(═X)ZR 5 ; R 5 represents a C1-C3 alkyl group optionally having one or more halogen atoms; Z represents a sulfur atom, NR 8 , or a direct bond; R 8 represents a C1-C3 alkyl group or a hydrogen atom; Q represents a pyrazolyl group optionally having a substituent; and W and X each independently represents an oxygen atom or a sulfur atom, has excellent control activity against pests.

  一种由化学式（1）表示的芳香化合物：其中R1和R2分别独立表示卤素原子、C1-C4烷基基团或C1-C4卤代烷基基团；m和n分别独立表示0至4的整数；R3和R4分别表示氢原子；Y表示化学式：—OC(═X)ZR5或—SC(═X)ZR5；R5表示一个C1-C3烷基基团，可选地具有一个或多个卤素原子；Z表示硫原子、NR8或直接键；R8表示一个C1-C3烷基基团或氢原子；Q表示一个吡唑基团，可选地具有一个取代基；W和X分别独立表示氧原子或硫原子，对害虫具有优异的控制活性。
• Process for producing a (fluoroalkylthio) acetonitrile
  申请人：Sumitomo Chemical Company, Limited

  公开号：EP2662355A1

  公开（公告）日：2013-11-13

  Disclosed is a process for producing a (fluoroalkylthio)acetonitrile of the formula (9): wherein R and R2 have the same meanings as defined below, which comprises converting a carbamoyl group (-CONH2) of fluoroalkylthioacetamide of the formula (8): wherein R represents a hydrogen atom or an alkyl group having 1 to 5 carbon atoms, and R2 represents a fluorine-containing alkyl group having 1 to 5 carbon atoms, into a cyano group (-CN). The compound of the formula (9) can be oxidized to obtain a nitrile compound of the formula (7): wherein R and R2 have the same meanings as above and n represents 1 or 2.

  本发明公开了一种生产式 (9) 的（氟烷硫基）乙腈的工艺： 其中 R 和 R2 与下文定义的含义相同，该工艺包括将式（8）的氟烷基硫代乙酰胺的氨基甲酰基（-CONH2）转化： 其中 R 代表氢原子或具有 1 至 5 个碳原子的烷基，R2 代表具有 1 至 5 个碳原子的含氟烷基。式（9）化合物经氧化后可得到式（7）的腈化合物： 其中 R 和 R2 的含义同上，n 代表 1 或 2。
• AROMATIC COMPOUND AND APPLICATION FOR SAME
  申请人：Sumitomo Chemical Company, Limited

  公开号：EP3081559A1

  公开（公告）日：2016-10-19

  wherein R1 and R2each independently represents a halogen atom, a C1-C4 alkyl group, or a C1-C4 haloalkyl group; m and n each independently represents an integer of 0 to 4; R3 and R4 each represents a hydrogen atom; Y represents formula: -OC(=X)ZR5 or -SC (=X) ZR5; R5 represents a C1-C3 alkyl group optionally having one or more halogen atoms; Z represents a sulfur atom, NR8, or a direct bond; R8 represents a C1-C3 alkyl group or a hydrogen atom; Q represents a pyrazolyl group optionally having a substituent; and W and X each independently represents an oxygen atom or a sulfur atom, has excellent control activity against pests.

  其中 R1 和 R2 各自独立地代表卤素原子、C1-C4 烷基或 C1-C4 卤代烷基；m 和 n 各自独立地代表 0 至 4 的整数；R3 和 R4 各自代表氢原子；Y 代表式：-OC(=X)ZR5或-SC(=X)ZR5；R5代表C1-C3烷基，可选择具有一个或多个卤原子；Z代表硫原子、NR8或直接键；R8代表C1-C3烷基或氢原子；Q代表吡唑基，可选择具有取代基；W和X各自独立地代表氧原子或硫原子，对害虫具有优异的防治活性。
• Pyrimidinyloxy benzene derivatives as herbicides
  申请人：FMC Corporation

  公开号：US11053204B2

  公开（公告）日：2021-07-06

  Disclosed are compounds of Formula 1, including all stereoisomers, N-oxides, and salts thereof, wherein A, Z, R1 R2, R3 and m are as defined in the disclosure. Also disclosed are compositions containing the compounds of Formula 1 and methods for controlling undesired vegetation comprising contacting the undesired vegetation or its environment with an effective amount of a compound or a composition of the invention.

  公开了式 1 的化合物，包括其所有立体异构体、N-氧化物和盐、 其中 A、Z、R1 R2、R3 和 m 如本公开中所定义。 本发明还公开了含有式 1 化合物的组合物，以及控制不良植被的方法，包括将有效量的本发明化合物或组合物与不良植被或其环境接触。
• USE OF VINPOCETINE DERIVATIVES FOR INHIBITING PRODUCTION OR SECRETION OF AMYLOID BETA PROTEIN
  申请人：Takeda Chemical Industries, Ltd.

  公开号：EP0813411B1

  公开（公告）日：2002-01-23