(3S,4R,5S)-5-Cyclohexyl-3-methoxymethoxy-heptane-1,4,5-triol | 141548-71-2

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: (3S,4R,5S)-5-Cyclohexyl-3-methoxymethoxy-heptane-1,4,5-triol
• CAS: 141548-71-2
• 化学式: C₁₅H₃₀O₅
• 分子量: 290.4
• InChiKey: DVSFEYRURMLNEC-ZNMIVQPWSA-N

物化性质

• 沸点：
  452.6±40.0 °C(Predicted)
• 密度：
  1.111±0.06 g/cm3(Predicted)

反应信息

• 作为产物：
  描述：

  (4S,5R)-5-((S)-1-Cyclohexyl-1-hydroxy-propyl)-4-methoxymethoxy-dihydro-furan-2-one 在 lithium aluminium tetrahydride 作用下， 生成 (3S,4R,5S)-5-Cyclohexyl-3-methoxymethoxy-heptane-1,4,5-triol
  参考文献：
  名称：

  Chelation Controlled Aldol Reaction of Tetronic Acid Dianion with Ketones

  摘要：

  The chelation effect in the aldol reaction of dianion of tetronic acid with ketones was investigated to give the erythro adduct, predominantly, via the six-membered chelation transition state. The carbon-carbon bond formation occurred at the 5-position siteselectively in this reaction.

  DOI：

  10.3987/com-91-s18