zinc meso-trans-di(9-anthryl)dihexadecyltetrabenzoporphyrinate | 1097651-58-5

• 分子结构分类: 有机化合物 - 木脂素、新木脂素和相关化合物 - 芳基萘木脂素
• 英文名称: zinc meso-trans-di(9-anthryl)dihexadecyltetrabenzoporphyrinate
• CAS: 1097651-58-5
• 化学式: C₉₆H₁₀₀N₄Zn
• 分子量: 1375.27
• InChiKey: GSCYWCSXUNQCPT-MNLAFJANSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  硬脂酸 、 3-[(1-oxo-1H-isoindol-3-yl)(9-anthryl)methylidene]-2,3-dihydro-1H-isoindol-1-one 在 zinc(II) oxide 作用下， 反应 0.5h， 以14%的产率得到zinc meso-trans-di(9-anthryl)dihexadecyltetrabenzoporphyrinate
  参考文献：
  名称：

  Meso-trans-diaryldihexadecyltetrabenzoporphyrins and their zinc complexes: Synthesis and spectra

  摘要：

  3-[(1-Oxo-1H-isoindol-3-yl)(phenyl)methylidene]-2,3-dihydro-1H-isoindol-1-one, 3-[(1-oxo-1H-isoindol-3-yl)(1-naphthyl)methylidene]-2,3-dihydro-1H-isoindol-1-one, and 3-[(1-oxo-1H-isoindol-3-yl)(9-anthryl)methylidene]-2,3-dihydro-1H-isoindol-1-one were prepared by the reactions of phthalimide with phenylacetic, 1-naphthylacetic, and 9-anthrylacetic acids, respectively. Heating of these precursors with stearic acid in the presence of zinc oxide yielded zinc complexes of meso-trans-diphenyldihexadecyltetrabenzoporphyrin, meso-trans-di(1-naphthyl)dihexadecyltetrabenzoporphyrin, and meso-trans-di(9-anthryl)dihexadecyltetrabenzoporphyrin, respectively. Treatment of the metal complexes with HCl yielded the porphyrin bases. The spectral properties of the compounds were studied.

  DOI：

  10.1134/s1070363207080257