2,8,12,18-tetraethyl-3,7,13,17-tetramethyl-5,15-bis(3'-hydroxyphenyl)porphyrin | 144913-69-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 四吡咯及其衍生物
• 英文名称: 2,8,12,18-tetraethyl-3,7,13,17-tetramethyl-5,15-bis(3'-hydroxyphenyl)porphyrin
• CAS: 144913-69-9
• 化学式: C₄₄H₄₆N₄O₂
• 分子量: 662.875
• InChiKey: QPVLXXCVOIJYMO-SVOHXFSLSA-N

反应信息

• 作为反应物：
  描述：

  1,6-二溴己烷 、 2,8,12,18-tetraethyl-3,7,13,17-tetramethyl-5,15-bis(3'-hydroxyphenyl)porphyrin 在 caesium carbonate 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 120.0h， 以6%的产率得到
  参考文献：
  名称：

  Face to face porphyrins as synthetic host molecules

  摘要：

  The bis-zincporphyrins 9 and 11 were prepared from the bis-(3'-hydroxyphenyl)-porphyrin 6. Both bis-zincporphyrins formed complexes in CHCl3 with a variety of amines and showed a strong preference for diamines, such as H2N(CH2)nNH2 and 4,4'-dipyridyl. The limited degree of chain length recognition for the diamine guests by both hosts is associated with conformational flexibility of both host and guest but the rigid guest, 4,4'-dipyridyl, is selectively complexed through operation of the chelate effect.

  DOI：

  10.1016/s0040-4020(01)90379-5