(5S,7S,8R,9R)-8-(4-Methoxy-benzyloxy)-5,7,9-trimethyl-tridecan-6-one | 151058-28-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (5S,7S,8R,9R)-8-(4-Methoxy-benzyloxy)-5,7,9-trimethyl-tridecan-6-one
• CAS: 151058-28-5
• 化学式: C₂₄H₄₀O₃
• 分子量: 376.58
• InChiKey: FGRXDDKLIYZXTH-UECWXEIQSA-N

反应信息

• 作为反应物：
  描述：

  (5S,7S,8R,9R)-8-(4-Methoxy-benzyloxy)-5,7,9-trimethyl-tridecan-6-one 在 2,3-二氯-5,6-二氰基-1,4-苯醌 作用下， 生成 (5S,7S,8R,9R)-8-Hydroxy-5,7,9-trimethyl-tridecan-6-one
  参考文献：
  名称：

  Studies on the alkylation of chiral enolates: application toward the total synthesis of discodermolide

  摘要：

  The alkylation of chiral enolates related to the C-16 to C-24 portion of discodermolide has been studied.

  DOI：

  10.1021/jo00074a005
• 作为产物：
  描述：

  (Z)-(7S,8R,9R)-8-(4-Methoxy-benzyloxy)-5,7,9-trimethyl-trideca-10,12-dien-6-one 在 platinum on activated charcoal 氢气 作用下， 生成 (5R,7S,8R,9R)-8-(4-Methoxy-benzyloxy)-5,7,9-trimethyl-tridecan-6-one 、 (5S,7S,8R,9R)-8-(4-Methoxy-benzyloxy)-5,7,9-trimethyl-tridecan-6-one
  参考文献：
  名称：

  Studies on the alkylation of chiral enolates: application toward the total synthesis of discodermolide

  摘要：

  The alkylation of chiral enolates related to the C-16 to C-24 portion of discodermolide has been studied.

  DOI：

  10.1021/jo00074a005