pentaammineiodorhodium(2+) | 15337-81-2

• 分子结构分类: 有机化合物 - 有机1,3-偶极化合物
• 英文名称: pentaammineiodorhodium(2+)
• CAS: 15337-81-2
• 化学式: H₁₅IN₅Rh
• 分子量: 314.963
• InChiKey: PKZPGXBDLXHINS-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
  None
• 环数：
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• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  pentaammineiodorhodium(2+) 生成 cis-{Rh(NH3)4I2}(1+)
  参考文献：
  名称：

  Charge-transfer photochemistry of rhodium (III)

  摘要：

  DOI：

  10.1021/ja00722a035

文献信息

• Kinetic studies on 4d and 5d transition metal complexes. Part I. The kinetics of the reactions of chloro-, bromo-, and iodo-pentammine-rhodium(iii) perchlorates with sodium hydroxide in aqueous solutions
  作者：G. W. Bushnell、G. C. Lalor、E. A. Moelwyn-Hughes

  DOI：10.1039/j19660000719

  日期：——

  The kinetics of the reactions [R(NH3)5X]2++ OH–→[R(NH3)5OH]2++ X–(X = Cl, Br, I) have been studied over a range of temperatures under conditions which allow the calculation of second-order rate constants at zero ionic strength.

  [R（NH 3）5 X] 2+ + OH – → [R（NH 3）5 OH] 2+ + X –（X = Cl，Br，I）的动力学研究允许在零离子强度下计算二级速率常数的条件下的温度。
• Metal ion assisted aquations—III[1] The silver ion assisted aquation of iodopentaamminerhodium(III) perchlorate
  作者：C.St.E. Boyce、G.C. Lalor、Hervine Miller

  DOI：10.1016/0022-1902(79)80280-8

  日期：1979.1

  The silver ion assisted aquation of [Rh(NH3)5I] (ClO4)2 has been explored in the temperature range 42–49°C, and for [Ag+] up to 1M. The observed pseudo-first-order rate constants are reported to be a relatively complicated function of [Ag+], viz.

  [Rh（NH 3）5 I]（ClO 4）2的银离子辅助水合物已经在42–49°C的温度范围内进行了研究，对于[Ag + ]高达1M。据报道，观察到的伪一阶速率常数是[Ag + ]的相对复杂的函数，即。
• The mercury(II)-induced aquation of chloro- and bromo-pentamminerhodium(III) perchlorates
  作者：S.C. Chan、S.F. Chan

  DOI：10.1016/0022-1902(72)80167-2

  日期：1972.7

  The second-order rate constants for the mercury(II)-induced aquation of [Rh(NH3)5X]2+ cations (where X = Cl or Br) have been measured in aqueous solution over a range of temperatures. The results are interpreted in terms of the formation of an activated complex RhXHg, which yields the aquopentamminerhodium(III) product by a unimolecular aquation with HgX+ as the leaving group. The effect of changing

  由汞（II）诱导的[Rh（NH 3）5 X] 2+阳离子（其中X = Cl或Br）的二阶速率常数已在一定温度范围内的水溶液中进行了测量。用活化的RhXHg络合物的形成来解释结果，该络合物通过以HgX +作为离去基团的单分子水合反应生成水合五氨合ho（III）产物。讨论了将X从Cl更改为Br对反应的活化焓的影响，并与相应的自发水合数据进行了比较。
• Structure and photochemical reactivity of excited states of halopentaamminerhodium(III) complexes
  作者：Timm L. Kelly、John F. Endicott

  DOI：10.1021/ja00756a052

  日期：1972.1
• Mechanism of photosubstitution in rhodium(III) chloroammines
  作者：Charles Kutal、Arthur W. Adamson

  DOI：10.1021/ic50124a058

  日期：1973.6.1