(Z)-7-[(1S,5R,6S,7R)-7-(tert-Butyl-diphenyl-silanyloxymethyl)-3-oxo-2,4-dioxa-bicyclo[3.2.1]oct-6-yl]-hept-5-enoic acid 2-trimethylsilanyl-ethyl ester | 147555-68-8

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: (Z)-7-[(1S,5R,6S,7R)-7-(tert-Butyl-diphenyl-silanyloxymethyl)-3-oxo-2,4-dioxa-bicyclo[3.2.1]oct-6-yl]-hept-5-enoic acid 2-trimethylsilanyl-ethyl ester
• CAS: 147555-68-8
• 化学式: C₃₅H₅₀O₆Si₂
• 分子量: 622.949
• InChiKey: UDKFEYICZHQKKI-QOYFVERWSA-N

物化性质

• 沸点：
  654.7±48.0 °C(predicted)
• 密度：
  1.09±0.1 g/cm3(Temp: 20 °C; Press: 760 Torr)(predicted)

反应信息

• 作为产物：
  描述：

  三光气 、 (Z)-7-[(1S,2R,3S,5R)-2-(tert-Butyl-diphenyl-silanyloxymethyl)-3,5-dihydroxy-cyclopentyl]-hept-5-enoic acid 2-trimethylsilanyl-ethyl ester 在 吡啶 作用下， 以 二氯甲烷 为溶剂， 以93%的产率得到(Z)-7-[(1S,5R,6S,7R)-7-(tert-Butyl-diphenyl-silanyloxymethyl)-3-oxo-2,4-dioxa-bicyclo[3.2.1]oct-6-yl]-hept-5-enoic acid 2-trimethylsilanyl-ethyl ester
  参考文献：
  名称：

  A safe and efficient method for conversion of 1,2- and 1,3-diols to cyclic carbonates utilizing triphosgene

  摘要：

  Reaction of triphosgene in the presence of pyridine with a variety of diols including hindered tertiary and 1,3-cyclic diols provided high yields of the corresponding cyclic carbonates.

  DOI：

  10.1016/0040-4039(93)85085-b