(R)-Methyl-phosphonic acid 2,4-di-tert-butyl-6-hydroxy-phenyl ester (S)-3-[(3,5-dinitro-benzoyl)-methyl-amino]-1,2,2-trimethyl-propyl ester | 137394-24-2

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: (R)-Methyl-phosphonic acid 2,4-di-tert-butyl-6-hydroxy-phenyl ester (S)-3-[(3,5-dinitro-benzoyl)-methyl-amino]-1,2,2-trimethyl-propyl ester
• CAS: 137394-24-2
• 化学式: C₂₉H₄₂N₃O₉P
• 分子量: 607.641
• InChiKey: ZIWODIHAFYLJGS-FGGXYXRSSA-N

反应信息

• 作为产物：
  描述：

  N-[(S)-3-(4,6-Di-tert-butyl-2-methoxy-2-methyl-1,3-dioxa-2λ⁵-phospha-indan-2-yloxy)-2,2-dimethyl-butyl]-N-methyl-3,5-dinitro-benzamide 在 盐酸 、 重氧水 作用下， 反应 0.33h， 生成 (S)-Methyl-phosphonic acid 2,4-di-tert-butyl-6-hydroxy-phenyl ester (S)-3-[(3,5-dinitro-benzoyl)-methyl-amino]-1,2,2-trimethyl-propyl ester 、 (R)-Methyl-phosphonic acid 2,4-di-tert-butyl-6-hydroxy-phenyl ester (S)-3-[(3,5-dinitro-benzoyl)-methyl-amino]-1,2,2-trimethyl-propyl ester
  参考文献：
  名称：

  Isolation and characterization of stereoisomers of pentacoordinated phosphorus. Hydrolysis of unsymmetrically substituted chiral monocyclic oxyphosphoranes

  摘要：

  DOI：

  10.1021/ja00024a056