sodium o-iodobenzoylglycilglycinate | 938446-71-0

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: sodium o-iodobenzoylglycilglycinate
• CAS: 938446-71-0
• 化学式: C₁₁H₁₀IN₂O₄*Na
• 分子量: 384.106
• InChiKey: QBJWMZIPQILORK-UHFFFAOYSA-M

反应信息

• 作为反应物：
  描述：

  2,2'-联吡啶 、 malachite 、 sodium o-iodobenzoylglycilglycinate 以 水 为溶剂， 生成 [Cu(o-iodobenzoylglycilglycinate)(2,2'-bipyridine)2]I*4H2O
  参考文献：
  名称：

  Models for thyroxine: Aromatic iodine-assisted self-assemblies

  摘要：

  Trying to understand the different recognition factors between thyroxine and its binding proteins, the chemistry of the ternary complexes between copper and o-iodobenzoylglycine (1-hip) [or o-iodobenzoylglycilglycine (B(I)GG)] as simple thyroxine models were studied lwith 2,2'-bipyridyl as secondary ligand.Two new compounds have been synthesized and structurally characterized: [Cu(1-hip)(bpy)(2)](+)(I-) center dot 1.5H(2)O and [Cu(B(I)GG)-(bpy)(2)](+)(I-) center dot 4H(2)O. These compounds and other previously reported by us offer interesting recognition patterns that could have biological relevance: iodine-iodine short interactions, iodine-hydrogen(aliphatic or aromatic) interactions, iodine-metal bonds, iodine-pi interactions (like C-H center dot center dot center dot pi), and aromatic self-assemblies assisted by iodine atoms. These patterns can be coupled in a synergistic manner, producing, for instance, a new C-I center dot center dot center dot pi center dot center dot center dot pi center dot center dot center dot I-C cluster pattern. (C) 2006 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2006.11.024