triethylammonium[N-(1-carboethoxy-2-thioethyl)[N-(2-thioethyl)-amino]acetimido]oxorhenate(V) | 195885-63-3

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: triethylammonium[N-(1-carboethoxy-2-thioethyl)[N-(2-thioethyl)-amino]acetimido]oxorhenate(V)
• CAS: 195885-63-3
• 化学式: C₆H₁₆N*C₉H₁₄N₂O₄ReS₂
• 分子量: 566.76
• InChiKey: QIEFEUFEXSWTQF-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  [ReOCl₃(PPh₃)₂] 、 N-(1-carboethoxy-2-thioethyl)[N-(2-thioethyl)amino]acetamide 在 Et₃N 作用下， 以 甲醇 为溶剂， 以23%的产率得到[N-(1-carboethoxy-2-thioethyl)[N-(2-thioethyl)amino]acetimido]oxorhenium(V)
  参考文献：
  名称：

  Synthesis and Characterization of Oxorhenium(V) Complexes with an Amine-Amide-Dithiol Ligand. X-Ray Crystal Structure of [N-(1-Carboethoxy-2-Thioethyl)-[N-(2-Thioethyl)amino]Acetimido]Oxorhenium(V)

  摘要：

  The preparation of N-(1-carboethoxy-2-thioethyl)[N-(2-thioethyl)amino]- acetamide (H4L) and its ligand-exchange reaction with ReO(PPh3)(2)Cl-3 are described. Two complexes, ReOHL and [Et3NH][ReOL], were formed depending on the extent of deprotonation of H4L during complexation. The structure of ReOHL was determined by single-crystal X-ray analysis. ReOHL crystallizes in the orthorhombic space group P2(1)2(1)2(1) with a = 10.4526(2) Angstrom, b = 11.5702(0) Angstrom, c = 12.0118(2) Angstrom, V = 1452.69(4) Angstrom(3), Z = 4, DC = 2.129 Mg/m(3), F(000) = 888 and R = 0.0216 for 2384 unique reflections. The coordination environment was approximately scquare-pyramidal with an amine N, a deprotonated amide N and two deprotonated thiol S atoms coordinated in the basal plane and the oxo ligand in the apical position.

  DOI：

  10.1080/00945719708000255