1-[(2,2-Dinitrobutoxy)methoxy]-2,2-dinitrobutane | 156270-33-6

• 分子结构分类: 有机化合物 - 有机1,3-偶极化合物 - 烯丙基型1,3-偶极有机化合物
• 英文名称: 1-[(2,2-Dinitrobutoxy)methoxy]-2,2-dinitrobutane
• 英文别名: 1-(2,2-dinitrobutoxymethoxy)-2,2-dinitrobutane
• CAS: 156270-33-6
• 化学式: C9H16N4O10
• 分子量: 340.24
• InChiKey: YQXWBIRMMNBGKA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.3
• 重原子数：
  23
• 可旋转键数：
  8
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  202
• 氢给体数：
  0
• 氢受体数：
  10

文献信息

• GEM-DINITRO ESTER ENERGETIC MATERIAL USING ESTERIFICATION AND PREPARATION METHOD THEREOF
  申请人：AGENCY FOR DEFENSE DEVELOPMENT

  公开号：US20150119599A1

  公开（公告）日：2015-04-30

  This invention relates to a gem-dinitro ester energetic material represented by Chemical Formula 1 below, which is synthesized using esterification, and to a preparation method thereof: wherein R is a C5˜C15 substituted or unsubstituted linear or branched alkyl group.

  这项发明涉及一种gem-二硝基酯能量材料，其化学式如下所示，通过酯化合成，其制备方法为：其中R为C5˜C15取代或未取代的直链或支链烷基基团。
• Process and intermediates for the production of BDNPA and BDNPF and other bis(dinitroalkyl)acetals and formals
  申请人：Rindone Renato R.

  公开号：US20090216049A1

  公开（公告）日：2009-08-27

  Bis(dinitroalkyl)acetals and formals having the formula (1) particularly bis(2,2-dinitropropyl)acetal and bis(2,2-dinitropropyl)formal are produced by oxidative nitration of compounds having the formula (2): preferably via a sodium or other alkali metal, or alkaline earth metal, salt of compounds of Formula (2). Certain of the compounds of formula (1) are novel. All of the intermediates of formula (2) are novel and form another aspect of this invention, as does a process for their production by reacting an aldehyde with a nitroalkanol. The process can readily produce a mixture of the dinitro compounds known as BDNPA and BDNPF (also known as A/F) using the non-explosive intermediates, BNPA and BNPF, both of which are novel.

  具有公式（1）的Bis（二硝基烷基）乙缩醛和缩甲醛，特别是Bis（2,2-二硝基丙基）乙缩醛和Bis（2,2-二硝基丙基）缩甲醛，通过化合物的氧化硝化制备，该化合物具有公式（2）的化合物，优选通过化合物的钠或其他碱金属或碱土金属盐的方式制备。公式（1）中的某些化合物是新颖的。公式（2）的所有中间体都是新颖的，并构成本发明的另一个方面，还包括通过将醛与硝基醇反应制备它们的过程。该过程可以轻松地使用非爆炸性中间体BNPA和BNPF（均为新颖化合物）产生BDNPA和BDNPF（也称为A / F）的二硝基化合物混合物。
• ENERGETIC PLASTICIZER FOR EXPLOSIVE CHARGES
  申请人：Rafael-Armament Development Authority Ltd.

  公开号：EP1805122A2

  公开（公告）日：2007-07-11
• Energetic Plasticizer For Explosive Charges
  申请人：Weitz Amir

  公开号：US20090020198A1

  公开（公告）日：2009-01-22

  An energetic material suitable for high-energy, plastic-bonded, explosive charges, the material including an energetic plasticizer containing an energetic nitrobutyl formal, wherein a composition of the energetic plasticizer contains at least 50%, by weight, of the energetic nitrobutyl formal.
• ACYCLIC ORGANONITRO COMPOUNDS FOR USE IN TREATING CANCER
  申请人：Scicinski Jan

  公开号：US20130053418A1

  公开（公告）日：2013-02-28

  The present invention provides acyclic, geminal-dinitro organic compounds, methods of synthesizing the compounds, pharmaceutical compositions, therapeutic methods, and medical kits for treating various conditions using such compounds and pharmaceutical compositions. The compounds and compositions are useful in the treatment of cancer.