3,3,4,4-Tetrafluorobutyl 2-methylprop-2-enoate | 138506-00-0

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: 3,3,4,4-Tetrafluorobutyl 2-methylprop-2-enoate
• CAS: 138506-00-0
• 化学式: C₈H₁₀F₄O₂
• 分子量: 214.16
• InChiKey: XZPZCHSPDJPFSV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.5
• 重原子数：
  14
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.62
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  6

文献信息

• METHOD OF PREPARING PHOTOACID GENERATING MONOMER
  申请人：Coley Suzanne M.

  公开号：US20120172619A1

  公开（公告）日：2012-07-05

  A method of preparing a monomer comprises reacting a sultone of the formula (I): wherein each R is independently F, C 1-10 alkyl, fluoro-substituted C 1-10 alkyl, C 1-10 cycloalkyl, or fluoro-substituted C 1-10 cycloalkyl, provided that at least one R is F; n is an integer of from 0 to 10, and m is an integer of 1 to 4+2n, with a nucleophile having a polymerizable group. Monomers, including a photoacid-generating monomer, may be prepared by this method.

  一种制备单体的方法包括将公式（I）的磺酮与具有聚合基团的亲核试剂反应，其中每个R独立地为F、C1-10烷基、氟取代的C1-10烷基、C1-10环烷基或氟取代的C1-10环烷基，但至少一个R为F；n为0至10的整数，m为1至4+2n的整数。通过这种方法可以制备单体，包括光酸生成单体。
• PHOTOACID GENERATING MONOMER AND PRECURSOR THEREOF
  申请人：Coley Suzanne M.

  公开号：US20120172555A1

  公开（公告）日：2012-07-05

  A monomer compound has the formula (I): where each R 1 , R 2 , and R 3 is independently H, F, C 1-10 alkyl, fluoro-substituted C 1-10 alkyl, C 1-10 cycloalkyl, or fluoro-substituted C 1-10 cycloalkyl, provided that at least one of R 1 , R 2 , or R 3 is F; n is an integer of from 1 to 10, A is a halogenated or non-halogenated C 2-30 olefin-containing polymerizable group, and G + is an organic or inorganic cation. The monomer is the reaction product of a sultone precursor and the oxyanion of a hydroxy-containing halogenated or non-halogenated C 2-30 olefin-containing compound. A polymer includes the monomer of formula (I).

  一种单体化合物具有以下化学式（I）：其中每个R1、R2和R3独立地是H、F、C1-10烷基、氟代C1-10烷基、C1-10环烷基或氟代C1-10环烷基，前提是R1、R2或R3中至少有一个是F；n是1到10之间的整数，A是卤代或非卤代的C2-30烯烃含有聚合基团，G+是有机或无机阳离子。该单体是砜前体和含有羟基的卤代或非卤代C2-30烯烃含有化合物的氧负离子的反应产物。聚合物包括化学式（I）的单体。
• Ink composition, ink composition for inkjet recording, inkjet recording method, and printed article obtained by inkjet recording method
  申请人：Fujifilm Corporation

  公开号：EP2236570B1

  公开（公告）日：2014-01-29
• US8716518B2
  申请人：——

  公开号：US8716518B2

  公开（公告）日：2014-05-06
• US8907122B2
  申请人：——

  公开号：US8907122B2

  公开（公告）日：2014-12-09