| 151138-78-2

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机磺酸及其衍生物
• CAS: 151138-78-2
• 化学式: C₃₈H₄₄F₆N₄O₆S₂Zr
• 分子量: 922.137
• InChiKey: JSTSSADKNIKQMF-SBYLDBAISA-L

反应信息

• 作为产物：
  描述：

  、 三氟甲磺酸三甲基硅酯 以 甲苯 为溶剂， 以71%的产率得到
  参考文献：
  名称：

  早期过渡金属卟啉：新颖的平面外顺式连接锆卟啉衍生物的合成，表征和反应性

  摘要：

  A new class of coordinatively unsaturated zirconium porphyrin compounds, (OEP)ZrR2 [OEP = dianion of octaethylporphyrin; R = chloride, trifluoromethanesulfonate (triflate, OTf), acetate, alkoxide, alkyl, aryl; R2 = cyclooctatetraenyl], has been prepared. (OEP)ZrCl2, prepared by metathesis between Li2OEP(DME)n and ZrCl4(DME), serves as starting material for further functionalization. The organometallic derivatives are very reactive, readily undergoing protonolysis, hydrogenolysis, and insertion of CO2 and acetone into the Zr-C bonds. Cis-ligation in these out-of-plane zirconium porphyrin compounds has been inferred from H-1 NMR measurements and confirmed in three derivatives by X-ray diffraction. Crystallographic data are as follows. (OEP)ZrCl2.0.5Tol: space group P1BAR with a = 9.870(2) angstrom, b = 14.143(3) angstrom, c = 14.498(3) angstrom, alpha = 66.257(17)-degrees, beta = 88.003(17)-degrees, gamma = 79.645(17)-degrees V = 1820.9(8) angstrom3, and Z = 2. (OEP)Zr(O(t)BU)2: space group P1BAR with a = 12.4441(12) angstrom, b = 13.1594(21) angstrom, c = 13.9541(18) angstrom alpha = 89.972(11)-degrees, beta = 99.192(9)-degrees, gamma = 115.487(11)-degrees V = 2045.7(10) angstrom3, and z = 2. (OEP)ZrMe2: space group P1BAR with a = 10.007(3) angstrom, b = 13.062(4) angstrom, c = 14.558(3) angstrom, alpha = 82.83(2)-degrees, beta = 88.24(2)-degrees, gamma = 79.98(2)-degrees, V = 1859.1(12) angstrom3, and Z = 2.

  DOI：

  10.1021/om00033a043