2-[4-[2-[4-[2-(2-Methylprop-2-enoyloxy)ethoxy]cyclohexyl]propan-2-yl]cyclohexyl]oxyethyl 2-methylprop-2-enoate | 68508-04-3

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: 2-[4-[2-[4-[2-(2-Methylprop-2-enoyloxy)ethoxy]cyclohexyl]propan-2-yl]cyclohexyl]oxyethyl 2-methylprop-2-enoate
• CAS: 68508-04-3
• 化学式: C₂₇H₄₄O₆
• 分子量: 464.6
• InChiKey: FBHYXKSGCYPHCM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.9
• 重原子数：
  33
• 可旋转键数：
  14
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.78
• 拓扑面积：
  71.1
• 氢给体数：
  0
• 氢受体数：
  6

文献信息

• PHOTOCURABLE COMPOSITION, CURED OBJECT, AND PROCESS FOR PRODUCING THE SAME
  申请人：MITSUBISHI CHEMICAL CORPORATION

  公开号：EP1275668A1

  公开（公告）日：2003-01-15

  The present invention has an object of providing a photocurable composition which can form a cured product that exhibits an improved mechanical strength while maintaining inherent properties such as low birefringence and heat resistance, a cured product comprising the same, and a process for producing the same. In other words, the present invention lies in (1) a photocurable composition comprising the following components A, B and C (with the proviso that the proportion of the various components each are represented relative to 100 parts by weight of the sum of the weight of the components A and B); (2) a cured product obtained by the copolymerization of the photocurable composition in the presence of a radical polymerization initiator; and (3) a process for producing the cured product which comprises the copolymerization of the photocurable composition in the presence of a radical polymerization initiator: Component A: 70 to 99 parts by weight of an alicyclic skeleton-containing bis(meth)acrylate represented by the general formula (I): (wherein R1 and R2 each independently represent a hydrogen atom or methyl group; m represents 1 or 2; n represents 0 or 1; and p and q each independently represent 0, 1 or 2); Component B: 1 to 30 parts by weight of an alicyclic skeleton-containing mono(meth)acrylate represented by the general formula (II): (wherein R3 represents a hydrogen atom or methyl group; m represents 1 or 2; n represents 0 or 1; and r and s each independently represent 0, 1 or 2); and Component C: 1 to 10 parts by weight of a mercapto compound having a functionality of at least two.

  本发明的目的是提供一种光固化组合物，该组合物可以形成一种固化物，该固化物在保持低双折射和耐热性等固有特性的同时，显示出更高的机械强度。 换句话说，本发明在于：(1) 一种光固化组合物，该组合物由以下组分 A、B 和 C 组成（附带条件是，各组分的比例相对于组分 A 和 B 重量总和的 100 重量份）；(2) 在有自由基聚合引发剂存在的情况下，通过共聚光固化组合物而获得的固化产物；以及 (3) 生产固化产物的工艺，该工艺包括在有自由基聚合引发剂存在的情况下共聚光固化组合物： 组分 A：70 至 99 重量份的含脂环族骨架的双(甲基)丙烯酸酯，由通式(I)代表： (其中 R1 和 R2 各自独立地代表氢原子或甲基；m 代表 1 或 2；n 代表 0 或 1；p 和 q 各自独立地代表 0、1 或 2）； 组分 B：1 至 30 份（按重量计）由通式(II)代表的含脂环族骨架的单（甲基）丙烯酸酯： (其中 R3 代表氢原子或甲基；m 代表 1 或 2；n 代表 0 或 1；r 和 s 各自独立地代表 0、1 或 2）；以及 组分 C：1 至 10 重量份的巯基化合物，其官能度至少为 2。
• FIBER COMPOSITE
  申请人：Mitsubishi Chemical Corporation

  公开号：EP2226171A1

  公开（公告）日：2010-09-08

  To provide a cellulose fiber composite having high transparency, low water absorption and low coefficient of linear thermal expansion. A fiber composite which comprises fibers having an average fiber diameter of at most 30 nm and a matrix material and which has a haze of at most 5 according to JIS K-7136 when the fiber composite has a thickness of 100 µm.

  提供一种具有高透明度、低吸水性和低线性热膨胀系数的纤维素纤维复合材料。 一种纤维复合材料，由平均纤维直径不超过 30 纳米的纤维和基体材料组成，当纤维复合材料的厚度为 100 微米时，根据 JIS K-7136 标准，雾度不超过 5。
• MODIFIED CELLULOSE FIBER AND CELLULOSE COMPLEX COMPRISING SAME
  申请人：Mitsubishi Chemical Corporation

  公开号：EP2441885A1

  公开（公告）日：2012-04-18

  An object of the invention is to provide cellulose fibers which can give a cellulose composite that renders high transparency, a reduction in linear expansion coefficient, and a high modulus of elasticity possible. The invention relates to: a process for producing modified cellulose fibers which includes a modification reaction step of reacting cellulose with an aromatic compound in an organic acid to thereby modify the cellulose with an aromatic-ring-containing substituent; cellulose fibers modified with aromatic-ring-containing substituent; a dispersion of the cellulose fibers; and a cellulose fiber composite obtained from the same.

  本发明的目的是提供一种纤维素纤维，它能使纤维素复合材料具有高透明度、降低线膨胀系数和高弹性模量。本发明涉及：一种生产改性纤维素纤维的工艺，该工艺包括一个改性反应步骤，即将纤维素与芳香族化合物在有机酸中反应，从而用含芳香环的取代基对纤维素进行改性；用含芳香环的取代基对纤维素纤维进行改性；纤维素纤维的分散体；以及由此获得的纤维素纤维复合材料。
• Photocurable composition, cured product and process for producing the same
  申请人：MITSUBISHI CHEMICAL CORPORATION

  公开号：US20030118941A1

  公开（公告）日：2003-06-26

  A photocurable composition, wherein a small amount of an alicyclic skeleton-containing mono(meth) acrylate is incorporated in a combination of an alicyclic skeleton-containing bis(meth)acrylate and a mercapto compound, a cured product obtained by the copolymerization thereof, and a process for producing the cured product.

  一种光固化组合物，其中在含脂环族骨架的双(甲基)丙烯酸酯和巯基化合物的组合物中加入了少量含脂环族骨架的单(甲基)丙烯酸酯，由其共聚得到固化产物，以及生产该固化产物的工艺。
• MODIFIED CELLULOSE FIBERS AND CELLULOSE COMPOSITE THEREOF
  申请人：AKAI Hideko

  公开号：US20120125547A1

  公开（公告）日：2012-05-24

  An object of the invention is to provide cellulose fibers which can give a cellulose composite that renders high transparency, a reduction in linear expansion coefficient, and a high modulus of elasticity possible. The invention relates to: a process for producing modified cellulose fibers which includes a modification reaction step of reacting cellulose with an aromatic compound in an organic acid to thereby modify the cellulose with an aromatic-ring-containing substituent; cellulose fibers modified with aromatic-ring-containing substituent; a dispersion of the cellulose fibers; and a cellulose fiber composite obtained from the same.