16-Methyl-heptadecanoic acid dimethylamide | 25563-78-4

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: 16-Methyl-heptadecanoic acid dimethylamide
• 英文别名: N,N,16-trimethylheptadecanamide
• CAS: 25563-78-4
• 化学式: C₂₀H₄₁NO
• 分子量: 311.552
• InChiKey: CXGQSFLQJOFDQN-UHFFFAOYSA-N

物化性质

• 沸点：
  188-194 °C(Press: 0.04 Torr)
• 密度：
  0.857±0.06 g/cm3(Temp: 20 °C; Press: 760 Torr)(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  7.8
• 重原子数：
  22
• 可旋转键数：
  15
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.95
• 拓扑面积：
  20.3
• 氢给体数：
  0
• 氢受体数：
  1

文献信息

• PROCESS FOR PRODUCING NITROGEN-CONTAINING COMPOUNDS
  申请人：Terasaka Michio

  公开号：US20100179349A1

  公开（公告）日：2010-07-15

  The present invention relates to a process for producing a tertiary amine by reducing an amide compound in the presence of a catalyst containing a sponge copper catalyst obtained by leaching alloy particles containing copper and aluminum and drying the thus leached alloy particles. The present invention provides a process for producing high-purity aliphatic tertiary amines containing a less amount of by-products at a high yield by subjecting aliphatic acid amides to hydrogenation reduction under solvent-free moderate conditions.

  本发明涉及一种在存在含有海绵铜催化剂的催化剂的情况下，通过还原酰胺化合物来生产三级胺的方法，所述海绵铜催化剂是通过浸出含有铜和铝的合金颗粒并干燥浸出的合金颗粒获得的。本发明提供了一种在无溶剂适度条件下将脂肪酸酰胺经过加氢还原处理以高产率产生含有少量副产物的高纯度脂肪族三级胺的方法。
• [EN] PROCESS FOR PRODUCING NITROGEN-CONTAINING COMPOUNDS<br/>[FR] PROCÉDÉ DE PRODUCTION DE COMPOSÉS AZOTÉS
  申请人：KAO CORP

  公开号：WO2009020244A1

  公开（公告）日：2009-02-12

  The present invention relates to a process for producing a tertiary amine in the presence of a catalyst containing copper and at least one element selected from the group consisting of elements belonging to Groups 2, 3, 7 and 12 of the Periodic Table (long form of the periodic table), said process including the steps of (a) reducing an amide compound in a hydrogen atmosphere; and (b) introducing a dialkyl amine containing a linear or branched alkyl group having 1 to 6 carbon atoms into a reaction product obtained in the step (a), and treating the reaction product with the dialkyl amine. The present invention provides a process for producing high-purity aliphatic tertiary amines containing a less amount of by-products by reducing aliphatic acid amides under moderate conditions using a chromium-free catalyst, as well as a process for producing amine derivatives such as amine oxide by using the aliphatic tertiary amines, with a good productivity in an economical manner.

  本发明涉及一种在含有铜和周期表长形式中属于2、3、7和12族元素之一的至少一种元素的催化剂存在下生产三级胺的方法，该方法包括以下步骤：(a) 在氢气氛中还原酰胺化合物；和(b) 将含有1至6个碳原子的线性或支链烷基基团的二烷基胺引入在步骤(a)中获得的反应产物中，并用二烷基胺处理反应产物。本发明提供了一种在中等条件下使用无铬催化剂还原脂肪酸酰胺从而生产含有较少副产物的高纯度脂肪族三级胺的方法，以及一种通过使用脂肪族三级胺生产胺氧化物等胺衍生物的方法，具有良好的经济生产能力。
• FILM FORMING COATING COMPOSITIONS CONTAINING CARBOXAMIDE COALESCING SOLVENTS AND METHODS OF USE
  申请人：Luebke Gary

  公开号：US20130143986A1

  公开（公告）日：2013-06-06

  A film may be formed from film forming compositions which comprise at least one carboxamide based coalescing solvent. These coalescing solvents impart equivalent or improved wet-scrub resistance, block resistance, gloss, dirt pick-up resistance and leveling characteristics to the films on a substrate, without contributing to total VOC levels, when replacing conventional coalescing solvents. The present invention also includes a method for forming a film comprising applying a film forming composition comprising polyunsaturated reactive carboxamides to a substrate and curing the film under ambient conditions. The coalescing carboxamide solvents are suitable for paint, latex based caulk, adhesives and floor care applications.

  可以使用至少一种基于羧酰胺的共溶剂来制备膜形成组合物，从而形成一种电影。当取代传统的共溶剂时，这些共溶剂可以赋予膜在基材上等效或改善的耐湿擦洗性、阻塞性、光泽度、防尘性和平整特性，而不会对总挥发性有所贡献。本发明还包括一种方法，用于形成膜，包括将含有多不饱和反应性羧酰胺的膜形成组合物涂覆在基材上，并在环境条件下固化膜。这些共溶剂适用于涂料、乳胶基密封胶、粘合剂和地面保养应用。
• METHOD OF PRODUCING NITROGEN-CONTAINING COMPOUND
  申请人：Kao Corporation

  公开号：EP2103594A1

  公开（公告）日：2009-09-23

  The present invention provides a process for producing high-purity aliphatic tertiary amines containing a less amount of by-products by using a chromium-free catalyst with a good productivity in an economically advantageous manner. The present invention relates to a process for producing a tertiary amine by reducing an amide compound in the presence of a catalyst containing copper and magnesium at a molar ratio of magnesium to copper (magnesium/copper) of from 0.01 to 20.

  本发明提供了一种使用无铬催化剂生产高纯度脂肪族叔胺的工艺，该工艺副产物少，生产率高，经济效益好。本发明涉及一种通过在含铜和镁的催化剂存在下还原酰胺化合物生产叔胺的工艺，镁与铜的摩尔比（镁/铜）为 0.01 至 20。
• Preparation of tertiary amine from an amide
  申请人：Kao Corporation

  公开号：EP2103594B1

  公开（公告）日：2014-12-03