| 1153624-25-9

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 香豆素及其衍生物
• CAS: 1153624-25-9
• 化学式: C₂₆H₄₁N₂O₇P
• 分子量: 524.594
• InChiKey: PWMZQYHSCJZHBM-UHFFFAOYSA-N

物化性质

• 沸点：
  677.9±55.0 °C(predicted)
• 密度：
  1.163±0.06 g/cm3(Temp: 20 °C; Press: 760 Torr)(predicted)

反应信息

• 作为反应物：
  描述：

  在 三氟乙酸 作用下， 以 二氯甲烷 为溶剂， 反应 6.0h， 以96%的产率得到4-[(7-diethylaminocoumarin-3-carbonyl)amino]butyl dihydrogen phosphate
  参考文献：
  名称：

  A Fluorescence Sensor for Detection of Geranyl Pyrophosphate by the Chemo-Ensemble Method

  摘要：

  Hexaamide receptor 4 and coumarin phosphate 5 form an ensemble for effective sensing of geranyl pyrophosphate (GPP). Fluorescence resonance energy transfer in the 4 + 5 ensemble diminishes when 5 is replaced by GPP. Receptor 4 binds selectively with GPP over other anions, including fatty acids. The 4-GPP complex in 1: 1 stoichiometry is inferred by NMR and fluorescence titrations. Receptor 4 contains a pseudotetrahedral cleft to accommodate GPP via Multiple hydrogen bonds, and the two aliphatic chains exert additional hydrophobic interactions.

  DOI：

  10.1021/jo802173b
• 作为产物：
  描述：

  在 叔丁基过氧化氢 、 三乙胺 作用下， 反应 8.0h， 生成
  参考文献：
  名称：

  A Fluorescence Sensor for Detection of Geranyl Pyrophosphate by the Chemo-Ensemble Method

  摘要：

  Hexaamide receptor 4 and coumarin phosphate 5 form an ensemble for effective sensing of geranyl pyrophosphate (GPP). Fluorescence resonance energy transfer in the 4 + 5 ensemble diminishes when 5 is replaced by GPP. Receptor 4 binds selectively with GPP over other anions, including fatty acids. The 4-GPP complex in 1: 1 stoichiometry is inferred by NMR and fluorescence titrations. Receptor 4 contains a pseudotetrahedral cleft to accommodate GPP via Multiple hydrogen bonds, and the two aliphatic chains exert additional hydrophobic interactions.

  DOI：

  10.1021/jo802173b