mono(tetramethylammonium) mono(tetrakis(phenylthio)cadmate(II)) | 82677-50-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: mono(tetramethylammonium) mono(tetrakis(phenylthio)cadmate(II))
• 英文别名: (Me4N)2[Cd(SPh)4]
• CAS: 82677-50-7
• 化学式: 2C₄H₁₂N*C₂₄H₂₀CdS₄
• 分子量: 697.389
• InChiKey: ROIDSTVRYIJVMV-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  9.29
• 重原子数：
  34.0
• 可旋转键数：
  8.0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  4.0

反应信息

• 作为反应物：
  描述：

  mono(tetramethylammonium) mono(tetrakis(phenylthio)cadmate(II)) 、 bis(triphenylphosphane)copper(I) nitrate 以 二氯甲烷 、 乙腈 为溶剂， 以65%的产率得到Cd(μ-SC6H5)4(Cu(P(C6H5)3)2)2
  参考文献：
  名称：

  Construction of heterobimetallic Cd(Hg)/Cu(Ag)/S(Se) complexes from homoleptic [Hg(EPh)2] molecules and [Cd(EPh)4]2− anions (E=S, Se)

  摘要：

  Treatment of [Hg(EPh)(2)] with 2 equivalents of [Cu(PPh3)(2)Cl] gave the trinuclear Hg/Cu/S(Se) complexes [Hg(mu-EPh)(2)(CuCl(PPh3)(2))] (E = S 1, Se 2) in which the two copper centers are ligated by the [PhE](-) ligands of the [Hg(EPh)(2)]. A similar reaction of [Hg(EPh)(2)] with [Ag(PPh3)(2)Cl] gave rise to isolation of the dinuclear compounds [Hg(SePh)(mu-SePh)(mu-Cl)Ag(PPh3)(2)] (E = S 3, Se 4) in which the coordination geometry of the mercury atom is a slightly distorted T-shape. Reactions of the homoleptic tetrahedral species [Cd(EPh)(4)](2-) with 2 equivalents of [Cu(PPh3)(2)NO3] afforded the neutral linear trinuclear complexes [Cd(mu-EPh)(4)[Cu(PPh3)(2))(2)](E = S 5, Se 6) in which two [Cu(PPh3)(2)](+) fragments bind with the opposite edges of a tetrahedral [Cd(EPh)(4)](2-) moiety via the sulfur or selenium atoms of the PhE- ligands. A similar reaction of [Me4N](2)[Cd(SPh)(4)] with 2 equivalents of [Ag(PPh3)(2)NO3] gave an analogous complex [Cd(mu-SPh)(4){Ag(PPh3)(2)}(2)] (7), whereas the reaction of [Me4N](2)[Cd(EPh)(4)] with an equivalent amount of [Ag(PPh3)(2)NO3] under similar conditions afforded the neutral heptanuclear complexes [Cd-3(mu-EPh)(6) (mu(3)-EPh)(4)(AgPPh3)(4)] (E = S 8, Se 9) which comprise three [(AgPPh3)](+) fragments side-ligated and one [(AgPPh3)](+) fragment side-capped with the trinuclear cadmium-thio(seleno)phenolate [Cd-3(mu-EPh)(9) (mu(3)-EPh)](4-) moieties via the sulfur atoms of thiophenolates in 8 and the selenium atoms of selenophenolates in 9. The nonlinear optical properties of two neutral heptanuclear complexes 8 and 9 have been examined by z-scan techniques with 7-ns pulses at 532 nm. (C) 2011 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2011.11.046
• 作为产物：
  描述：

  cadmium(II) nitrate tetrhydrate 、 四甲基氯化铵 、 苯硫酚 在 (C₄H₉)3N 作用下， 以 甲醇 为溶剂， 生成 mono(tetramethylammonium) mono(tetrakis(phenylthio)cadmate(II))
  参考文献：
  名称：

  Wilker, Jonathan J.; Lippard, Stephen J., Inorganic Chemistry, 1997, vol. 36, # 6, p. 969 - 978

  摘要：

  DOI：

文献信息

• The metal NMR spectra of thiolate and phenylselenolate complexes of zinc(II) and mercury(II)
  作者：Geetha K. Carson、Philip A.W. Dean

  DOI：10.1016/s0020-1693(00)85806-5

  日期：1982.1
• Syntheses, properties, and molecular and crystal structures of (Me4N)4[E4M10(SPh)16] (E = sulfur or selenium; M = zinc or cadmium): molecular supertetrahedral fragments of the cubic metal chalcogenide lattice
  作者：Ian G. Dance、Anna Choy、Marcia L. Scudder

  DOI：10.1021/ja00333a030

  日期：1984.10