{triphenylphosphine(2,3,7,8,12,13,17,18-octamethyl-5,10,15-triphenylcorrolato)cobalt(III)} | 147342-56-1

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二苯乙烯类
• 英文名称: {triphenylphosphine(2,3,7,8,12,13,17,18-octamethyl-5,10,15-triphenylcorrolato)cobalt(III)}
• CAS: 147342-56-1
• 化学式: C₆₃H₅₄CoN₄P
• 分子量: 957.116
• InChiKey: FALMAGHVHCWCSL-KNUKPZIDSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  {triphenylphosphine(2,3,7,8,12,13,17,18-octamethyl-5,10,15-triphenylcorrolato)cobalt(III)} 以 苯甲腈 为溶剂， 生成 (5,10,15-triphenyl-2,3,7,8,12,13,17,18-octamethylcorrolato)cobalt(II)(1-)
  参考文献：
  名称：

  Adamian, Victor A.; D'Souza, Francis; Licoccia, Silvia, Inorganic Chemistry, 1995, vol. 34, # 3, p. 532 - 540

  摘要：

  DOI：
• 作为产物：
  描述：

  cobalt(II) acetate 、 苯甲醛 、 phenylmethanebis(3,4-dimethylpyrrol-5-yl-2-carboxylic acid) 在 三苯基膦 、 2,3-二氯-5,6-二氰基-1,4-苯醌 作用下， 以 二氯甲烷 、 三氟乙酸 为溶剂， 以18%的产率得到{triphenylphosphine(2,3,7,8,12,13,17,18-octamethyl-5,10,15-triphenylcorrolato)cobalt(III)}
  参考文献：
  名称：

  Synthesis and characterization of cobalt(III) complexes of meso-phenyl-substituted corroles

  摘要：

  The synthesis and characterization of two new cobalt(III) complexes of corrole: [triphenylphosphine-(2,3,7,8,12,13,17,18-octamethyl-10-phenylcorrolato)cobalt(III)] and [triphenylphosphine(2,3,7,8,12,13,17,18-octa-methyl-5,10,15-triphenylcorrolato)cobalt(III) are reported. Such complexes represent the first examples of meso-substituted corrolates reported in the literature. The insertion of one or three phenyl groups at the meso-positions of the macrocyclic ligand has been achieved by designing different synthetic strategies. The spectroscopic characterization of the complexes shows the peculiarity of the corrole ligand which maintains a planar structure despite the steric hindrance of the peripheral substituents.

  DOI：

  10.1016/s0020-1693(00)82913-8

文献信息

• Paolesse, Roberto; Licoccia, Silvia; Bandoli, Giuliano, Inorganic Chemistry, 1994, vol. 33, # 6, p. 1171 - 1176
  作者：Paolesse, Roberto、Licoccia, Silvia、Bandoli, Giuliano、Dolmella, Alessandro、Boschi, Tristano

  DOI：——

  日期：——