[nickel(II)(N,N'-1,2-cyclohexenylenebis(salicylideneimine)] | 39019-42-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [nickel(II)(N,N'-1,2-cyclohexenylenebis(salicylideneimine)]
• CAS: 39019-42-6
• 化学式: C₂₀H₁₈N₂NiO₂
• 分子量: 377.065
• InChiKey: HKHMFVWLSANPLB-JKBLJYNNSA-L

反应信息

• 作为产物：
  描述：

  水杨醛 、 nickel(II) acetate tetrahydrate 、 (1R,2R)-1,2-diaminocyclohexane 以 乙醇 为溶剂， 生成 [nickel(II)(N,N'-1,2-cyclohexenylenebis(salicylideneimine)]
  参考文献：
  名称：

  Synthesis, Crystal Structure and Theoretical Calculation of Ni(II) Complex with N,N′‐1,2‐Cyclohexenylenebis (salicylideneimine)

  摘要：

  A complex [Ni(C20H18N2O2)] [C20H18N2O2: N,N'-1,2-cyclohexenylenebis(salicylid-eneimine)] has been synthesized and characterized by IR, elemental analysis and X-ray diffraction single crystal analysis. The crystal crystallizes in monoclimc space group P2(1)/c with a = 10.998(2) angstrom, b = 12.774(3) angstrom, c = 12.370(3) angstrom, alpha = 90 degrees, beta = 95.31(3)degrees, gamma = 90 degrees, V = 1.7304(8)nm(3), Z = 4, F(000) = 832, S = 1.272, Dc = 1.447 g.cm(-3), R-1 = 0.1027, wR(2) = 0.2136, mu = 1.136 mm(-1). The Ni(H) is four coordinated by two nitrogen and two oxygen atoms from the Schiff base ligand to furnish a planar quadrilateral geometry. The molecules are connected by hydrogen bonds to form a three-dimensional network structure. The theoretical studies of the title complex were carried out by density functional theory(DFT) B3LYP method & 8226; CCDC: 287808.

  DOI：

  10.1080/15533170601172518