[Cd(benzophenone-4,4'-dicarboxylate)(4,4'-bipyridine)]*(dimethylformamide)*H2O | 1039055-63-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [Cd(benzophenone-4,4'-dicarboxylate)(4,4'-bipyridine)]*(dimethylformamide)*H2O
• CAS: 1039055-63-4
• 化学式: C₃H₇NO*C₁₀H₈N₂*C₁₅H₈O₅*Cd*H₂O
• 分子量: 627.932
• InChiKey: JHIUMRAQKXSLPB-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  0.67
• 重原子数：
  39.0
• 可旋转键数：
  6.0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.07
• 拓扑面积：
  174.92
• 氢给体数：
  0.0
• 氢受体数：
  8.0

反应信息

• 作为反应物：
  描述：

  [Cd(benzophenone-4,4'-dicarboxylate)(4,4'-bipyridine)]*(dimethylformamide)*H2O 以 neat (no solvent) 为溶剂， 生成 [Cd(benzophenone-4,4'-dicarboxylate)(4,4'-bipyridine)]
  参考文献：
  名称：

  柔性多孔配位聚合物的动力学开门过程。

  摘要：

  DOI：

  10.1002/anie.200705822
• 作为产物：
  描述：

  4,4'-联吡啶 、 cadmium(II) nitrate tetrhydrate 、 二苯甲酮-4,4'-二甲酸 、 N,N-二甲基甲酰胺 以 N,N-二甲基甲酰胺 为溶剂， 生成 [Cd(benzophenone-4,4'-dicarboxylate)(4,4'-bipyridine)]*(dimethylformamide)*H2O
  参考文献：
  名称：

  柔性多孔配位聚合物的动力学开门过程。

  摘要：

  DOI：

  10.1002/anie.200705822

文献信息

• Isophthalate–Hydrazone 2D Zinc–Organic Framework: Crystal Structure, Selective Adsorption, and Tuning of Mechanochemical Synthetic Conditions
  作者：Kornel Roztocki、Damian Jędrzejowski、Maciej Hodorowicz、Irena Senkovska、Stefan Kaskel、Dariusz Matoga

  DOI：10.1021/acs.inorgchem.6b01405

  日期：2016.10.3

  A new layered mixed-linker metal organic framework [Zn-2(iso)(2)(pcih)(2)](n) (MOF) built from isophthalate ions (iso(2-)) and 4-pyridinecarbaldehyde isonicotinoyl hydrazone (pcih) was prepared using both solution and mechanochemical methods. By use of the latter, the 2D MOF is obtained either in a one-mortar three-component grinding or on the way of a two-step mechanosynthesis. Tuning of mechanochemical synthetic conditions allowed 118 to identify both necessary and favorable factors for the solid-state formation of the MOF. Single-crystal X-ray diffraction reveals the presence of interdigitated layers in the ABAB. arrangement and interlayer OD cavities-filled With ::guest molecules. Upon thermal activation, the dynamic framework exhibits stepwise and selective adsorption of CO2 over N-2 as well as high-pressure H-2 adsorption reaching maximum excess of 1.15 wt% at 77 K. The mechanochemical synthetic protocol is expanded to a few other interdigitated structures.