Hexadecafluoroct-4-en | 35844-81-6

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 乙烯基卤化物
• 英文名称: Hexadecafluoroct-4-en
• 英文别名: hexadecafluoro-oct-4-ene；1,1,1,2,2,3,3,4,5,6,6,7,7,8,8,8-Hexadecafluorooct-4-ene
• CAS: 35844-81-6
• 化学式: C₈F₁₆
• 分子量: 400.062
• InChiKey: DJGAMLSXFFGRHU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.2
• 重原子数：
  24
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.75
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  16

文献信息

• Method of Hydrodechlorination to Produce Dihydrofluorinated Olefins
  申请人：Nappa Mario Joseph

  公开号：US20090012335A1

  公开（公告）日：2009-01-08

  Disclosed herein is a process for the preparation of fluorine-containing olefins comprising contacting a chlorofluoroalkene with hydrogen in the presence of a catalyst at a temperature sufficient to cause replacement of the chlorine substituents with hydrogen. Also disclosed is a catalyst composition for the hydrodechlorination of chlorofluoroalkenes comprising copper metal deposited on a support.

  本文揭示了一种制备含氟烯烃的过程，包括在存在催化剂的情况下，将氯氟烯烃与氢气接触，以使氯取代物被氢取代的温度足够高。还揭示了一种用于氯氟烯烃的氢脱氯催化剂组合物，其中铜金属沉积在一种载体上。
• Process for producing fluorinated aliphatic compounds
  申请人：——

  公开号：US20020177742A1

  公开（公告）日：2002-11-28

  The present invention relates to a process for producing fluorinated aliphatic compounds by pyrolysis of perfluorocarboxylic acids and their derivatives—halides and esters. The pyrolysis is carried out in the presence of a catalyst consisting of a carrier most preferably selected from the series comprising active carbon, magnesium oxide, calcium oxide, barium oxide, zinc oxide, aluminum oxide, nickel oxide, oxides of silicon promoted with alkali metal halides, selected from the series comprising fluorides, chlorides bromides, iodides of sodium, potassium, rubidium, cesium, at a temperature in the range of from about 100° C. to about 450° C.; with producing fluorinated aliphatic compounds selected from the series comprising perfluoroolefins, polyfluoroolefins and their derivatives; and also in the presence additionally of hydrogen fluoride with the formation of fluorinated aliphatic compounds selected from the series comprising polyfluoroalkanes and their derivatives.

  本发明涉及一种通过对全氟羧酸及其衍生物（卤化物和酯类）进行热解制备氟代脂肪化合物的过程。在催化剂的存在下进行热解，该催化剂由载体组成，最好选择活性炭、氧化镁、氧化钙、氧化钡、氧化锌、氧化铝、氧化镍、硅氧化物（促进碱金属卤化物选择自钠、钾、铷、铯的氟化物、氯化物、溴化物、碘化物系列）中最好的一种。在温度范围约为100℃至450℃的条件下进行，生产出选择自全氟烯烃、多氟烯烃及其衍生物的氟代脂肪化合物；此外，还在氢氟酸的存在下形成选择自多氟烷和其衍生物的氟代脂肪化合物。
• METHOD OF HYDRODECHLORINATION TO PRODUCE DIHYDROFLUORINATED OLEFINS
  申请人：NAPPA MARIO JOSEPH

  公开号：US20090240089A1

  公开（公告）日：2009-09-24

  Disclosed herein is a process for the preparation of fluorine-containing olefins comprising contacting a chlorofluoroalkene with hydrogen in the presence of a catalyst at a temperature sufficient to cause replacement of the chlorine substituents with hydrogen. Also disclosed is a catalyst composition for the hydrodechlorination of chlorofluoroalkenes comprising copper metal deposited on a support.

  本文公开了一种制备含氟烯烃的方法，包括在催化剂存在下将氯氟烯与氢接触，使氯取代物被氢取代的温度足够高。还公开了一种用于氯氟烯的脱氯催化剂组合物，其中铜金属被沉积在支撑体上。
• Stable emulsions of highly fluorinated organic compound
  申请人：CHILDREN'S HOSPITAL MEDICAL CENTER

  公开号：EP0231091A1

  公开（公告）日：1987-08-05

  Stable emulsions of highly fluorinated organic compounds for use as oxygen transport agents, "artificial bloods" or red blood cell substitutes and as contrast agents for biological imaging. The emulsions comprise a highly fluorinated organic compound, an oil that is not substantially surface active and not significantly soluble in water, a surfactant and water.

  高氟有机化合物的稳定乳剂，可用作氧运输剂、"人造血液 "或红细胞替代物以及生物成像的造影剂。乳剂由高氟有机化合物、表面活性不强且不太溶于水的油类、表面活性剂和水组成。
• Paramagnetic particles that provide improved relaxivity
  申请人：——

  公开号：US20030185760A1

  公开（公告）日：2003-10-02

  An improved contrast agent for magnetic resonance imaging comprises particles to each of which is coupled a multiplicity of chelating agents containing paramagnetic ions. In the improved agent, the position of the ion is offset from the surface of the particle so as to improve the relaxivity imparted by the contrast agent.

  一种用于磁共振成像的改进型造影剂由颗粒组成，每个颗粒上都耦合了多种含有顺磁离子的螯合剂。在改进型造影剂中，离子的位置偏离颗粒表面，以提高造影剂的弛豫性。