1,4-Cyclohexylen-diacrylat | 34869-20-0

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: 1,4-Cyclohexylen-diacrylat
• 英文别名: 1,4-cyclohexanediol diacrylate；(4-Prop-2-enoyloxycyclohexyl) prop-2-enoate
• CAS: 34869-20-0
• 化学式: C₁₂H₁₆O₄
• 分子量: 224.257
• InChiKey: OAKFFVBGTSPYEG-UHFFFAOYSA-N

物化性质

• 沸点：
  289.3±33.0 °C(Predicted)
• 密度：
  1.08±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.5
• 重原子数：
  16
• 可旋转键数：
  6
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  52.6
• 氢给体数：
  0
• 氢受体数：
  4

文献信息

• Acrylic Acid-Based Polymer and Method of Producing the Same
  申请人：Kubo Hideo

  公开号：US20090111961A1

  公开（公告）日：2009-04-30

  Disclosed are an acrylic acid-based polymer which is a star polymer containing a repeating unit derived from an (α-lower alkyl)acrylic ester represented by formula (I): (wherein R 1 represents a hydrogen atom or a lower alkyl group, and R 2 represents an organic group having a polar group) in an arm portion; an acrylic acid-based polymer containing a repeating unit derived from an poly(α-lower alkyl)acrylic ester and a repeating unit derived from an (α-lower alkyl)acrylic ester represented by formula (I), and a method for producing a polymer through living polymerization, comprising forming an oligomer having a polymerization active end, which is an oligomer higher than an average 1.0-mer and lower than an average 4.0-mer or an average 4.0-mer, and polymerizing using the oligomer having a polymerization active end as an initiating species.

  本发明涉及一种基于丙烯酸的星型聚合物，其包含来自式（I）所表示的（α-较低烷基）丙烯酸酯的重复单元的臂部分；以及一种基于丙烯酸的聚合物，其包含来自聚（α-较低烷基）丙烯酸酯和式（I）所表示的（α-较低烷基）丙烯酸酯的重复单元，并且本发明还提供了通过活性聚合制备聚合物的方法，包括形成具有聚合活性端的寡聚体，该寡聚体高于平均1.0-聚体但低于平均4.0-聚体或平均4.0-聚体，并以具有聚合活性端的寡聚体作为引发物种进行聚合。
• ACRYLIC ACID-BASED POLYMER AND METHOD OF PRODUCING THE SAME
  申请人：Kubo Hideo

  公开号：US20110046333A1

  公开（公告）日：2011-02-24

  Disclosed are an acrylic acid-based polymer which is a star polymer containing a repeating unit derived from an (α-lower alkyl)acrylic ester represented by formula (I): (wherein R 1 represents a hydrogen atom or a lower alkyl group, and R 2 represents an organic group having a polar group) in an arm portion; an acrylic acid-based polymer containing a repeating unit derived from an poly(α-lower alkyl)acrylic ester and a repeating unit derived from an (α-lower alkyl)acrylic ester represented by formula (I), and a method for producing a polymer through living polymerization, comprising forming an oligomer having a polymerization active end, which is an oligomer higher than an average 1.0-mer and lower than an average 4.0-mer or an average 4.0-mer, and polymerizing using the oligomer having a polymerization active end as an initiating species.

  本文揭示了一种基于丙烯酸的星形聚合物，其包含由公式(I)表示的(α-低烷基)丙烯酸酯衍生的重复单元的臂部分；一种基于丙烯酸的聚合物，其中包含由聚(α-低烷基)丙烯酸酯和由公式(I)表示的(α-低烷基)丙烯酸酯衍生的重复单元，并且通过活性聚合法制备聚合物的方法，包括形成具有聚合活性端的寡聚物，该寡聚物高于平均1.0-聚体但低于平均4.0-聚体或平均4.0-聚体，并使用具有聚合活性端的寡聚物作为引发物种进行聚合。
• Process for preparing aqueous dispersions of acrylic-urethane graft copolymers
  申请人：Polyvinyl Chemie Holland B.V.

  公开号：EP0167188A1

  公开（公告）日：1986-01-08

  Ethylenically unsaturated aqueous urethane dispersions of controlled molecular weight are prepared by first reacting an active hydrogen atom containing polymerizable vinyl compound with a diisocyanate. The adduct thus formed. being a nearly selectively made mono-ethylenically unsaturated mono-isocyanate compound, is used in preparing an aqueous urethane polymer dispersion by reacting this adduct with polyisocyanates, organic compounds containing active hydrogen atoms like polyols and polyamines and organic compounds containing at least one active hydrogen atom and at least one group capable of saltformation. foiiowed by neutralizing, dispersing in water ano chain-extending the prepolymer. This ethyienically unsaturated aqueous urethane polymer dispersion is subjected to an emulsionpolymerization by conventional techniques with acrylate, methacrylate and related polymerizable compounds, yielding an aqueous dispersion of an urethane-acrylate graft copolymer. These urethane-acrylate graft copolymers are particularly useful as binders for coatings, printing inks and related applications.

  首先将含有活性氢原子的可聚合乙烯基化合物与二异氰酸酯反应，制备分子量可控的乙烯基不饱和聚氨酯水性分散体。 这样形成的加成物是一种近乎选择性的单乙烯不饱和单异氰酸酯化合物，可用于制备水性聚氨酯聚合物分散体，方法是将这种加成物与多异氰酸酯、含活泼氢原子的有机化合物（如多元醇和多胺）以及含至少一个活泼氢原子和至少一个能盐化的基团的有机化合物反应。 这种乙烯基不饱和聚氨酯聚合物水性分散体通过传统技术与丙烯酸酯、甲基丙烯酸酯及相关可聚合化合物进行乳液聚合，得到聚氨酯-丙烯酸酯接枝共聚物的水性分散体。 这些氨基甲酸乙酯-丙烯酸酯接枝共聚物特别适合用作涂料、印刷油墨和相关应用的粘合剂。
• Process for the cementing of photopolymerizable flexographic printing elements or printing plates
  申请人：E.I. DU PONT DE NEMOURS AND COMPANY

  公开号：EP0230889A2

  公开（公告）日：1987-08-05

  A process is described for cementing together the edges of photopolymerizable flexographic printing elements or printing plates that contain as an elastomeric binder a block copolymer whose polymer blocks are polystyrene and polyisoprene and/or polybutadiene or their copolymers.

  描述了一种将可感光聚合的柔版印刷元件或印版的边缘粘合在一起的工艺，这些元件或印版含有嵌段共聚物作为弹性粘合剂，嵌段共聚物的聚合物块是聚苯乙烯和聚异戊二烯和/或聚丁二烯或它们的共聚物。
• Durch Photopolymerisation vernetzbare Gemische
  申请人：BASF Aktiengesellschaft

  公开号：EP0223114A2

  公开（公告）日：1987-05-27

  Durch Photopolymerisation vernetzbare Gemische auf der Grundlage von Bin­demitteln, hiermit verträglichen photopolymerisierbaren Monomeren und Photoinitiatoren, enthaltend als Bindemittel Copolymerisate, hergestellt aus a₁) 30 bis 70 Gew.% Ethylen, a₂) 5 bis 40 Gew.% (Meth)Acrylsäure und a₃) 5 bis 50 Gew.% mindestens eines Vinylesters, Vinylethers, (Meth)Acrylsäureesters und/oder (Meth)Acrylsäure­amids.

  以粘合剂、与之相容的可光聚合单体和光引发剂为基础的可通过光聚合交联的混合物，其中包含由以下物质制备的共聚物作为粘合剂： a₁) 30-70%（重量）的乙烯、a₂) 5-40%（重量）的（甲基）丙烯酸和 a₃) 5-50%（重量）的至少一种乙烯基酯、乙烯基醚、（甲基）丙烯酸酯和/或（甲基）丙烯酸酰胺。