| 832118-44-2

• CAS: 832118-44-2
• 化学式: C₁₈H₁₀Cl₂MnNO₄
• 分子量: 430.126
• InChiKey: LOTGLUZZWKCRAL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  pentacarbonyl(methyl)manganese(I) 、 2,6-Cl2C6H3CH=NCH2Ph 以 正辛烷 为溶剂， 以12%的产率得到
  参考文献：
  名称：

  Regioselective cyclomanganation of Schiff bases. An unexpected effect of chloro substituents

  摘要：

  In this paper we describe the synthesis of new metallacycles by the cyclomanganation reaction of benzyl-benzylidene-amines by using [MnMe(CO)(5)] as metallating agent. These ligands can undergo metallation on different aromatic carbon atoms but no important differences have been found in the regioselectivity of the process, that can be related to the electronic effect of the substituents. and in all the cases studied the endo-cyclomanganated complexes of para-substituted imines have been obtained. The corresponding exo-metallacycles were obtained by reaction of [MnMe(CO)(5)] on the imine 2.6-Ch(2)C(6)H(3)CH=NCH2Ph and 2,4,6-Me(3)C(6)Hr(2) -CH=NCH2Ph, derived from 2,6-dichlorobenzaldehyde and 2,4,6-trimethylbenzaldehyde, respectively.The results described suggest that the mechanism of the cyclomanganation is similar to that of cyclopalladation and it can be proposed that cyclomanganation takes place by the formation of a four-centered transition state, involving the C-H and Mn-C-acetyl bonds in the acetyl coordination complex formed in the first step of the reaction. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2004.07.010