[cadmium(II)(4-bromo-2-[(2-piperazinylethylimino)methyl]phenol)(nitrate)2(H2O)] methanol monosolvate | 1245707-55-4

• 分子结构分类: 有机化合物 - 有机杂环化合物
• 英文名称: [cadmium(II)(4-bromo-2-[(2-piperazinylethylimino)methyl]phenol)(nitrate)2(H2O)] methanol monosolvate
• CAS: 1245707-55-4
• 化学式: CH₄O*C₁₃H₂₀BrCdN₅O₈
• 分子量: 598.687
• InChiKey: VBYLHWHTJYBJIH-BADOYKKRSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  cadmium(II) nitrate tetrhydrate 、 2-((2-(piperazin-1-yl)ethylimino)methyl)-4-bromophenol 以 甲醇 为溶剂， 以45%的产率得到[cadmium(II)(4-bromo-2-[(2-piperazinylethylimino)methyl]phenol)(nitrate)2(H2O)] methanol monosolvate
  参考文献：
  名称：

  Synthesis, Crystal Structures, and Urease Inhibitory Activities of Two Isostructural Schiff Base Cadmium(II) Complexes

  摘要：

  Two isostructural cadmium(II) complexes, [Cd(L1)(NO3)2 (H2O)] center dot CH3OH (1) and [Cd(L2)(NO3)2(H2O)] center dot CH3OH (2), derived from the Schiff bases 4-bromo-2-[(2-piperazinylethylimino)methyl]phenol (L1) and 4-chloro-2-[(2-piperazinylethylimino)methyl]phenol (L2), respectively, were prepared and structurally characterized by X-ray diffraction. Each complex consists of a mononuclear cadmium(II) complex molecule and a methanol molecule of crystallization. The Cd atom in each complex is six-coordinated by one phenolate O, one imine N and one amine N atoms of the Schiff base ligand, two O atoms from two nitrate anions, and one water O atom, forming distorted octahedral coordination. The urease inhibitory activities of the complexes were evaluated.

  DOI：

  10.1080/15533174.2010.487057