[Ni3(N3)3(O2CMe)3(pyridine)5] | 910624-64-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: [Ni3(N3)3(O2CMe)3(pyridine)5]
• 英文别名: [Ni3(N3)3(O2CMe)3(py)5]；Nickel(2+);pyridine;triacetate;triazide；nickel(2+);pyridine;triacetate;triazide
• CAS: 910624-64-5
• 化学式: C₃₁H₃₄N₁₄Ni₃O₆
• 分子量: 874.771
• InChiKey: VFKUUACVDRYHBH-UHFFFAOYSA-K

反应信息

• 作为产物：
  描述：

  吡啶 、 sodium azide 、 nickel(II) acetate tetrahydrate 以 吡啶 、 甲醇 为溶剂， 以55%的产率得到[Ni3(N3)3(O2CMe)3(pyridine)5]
  参考文献：
  名称：

  High-Spin M²⁺ Carboxylate Triangles from the Microwave

  摘要：

  The reaction of M(O2CMe)(2), 4H(2)O (M) Ni, Co) with NaN3 in pyridine/MeOH under microwave irradiation and controlled pressure/temperature leads to the formation of the trimetallic species [M-3-(N-3)(3)(O2CMe)(3)(py)(5)] (M) Ni, 1; Co, 2) in 4 min and in high yields. Both complexes display dominant ferromagnetic interactions and high-spin ground states.

  DOI：

  10.1021/ic061035o

文献信息

• Microwave heating – A new synthetic tool for cluster synthesis
  作者：Constantinos J. Millos、A. Gavin Whittaker、Euan K. Brechin

  DOI：10.1016/j.poly.2006.09.072

  日期：2007.6

  Microwave heating is a new and extremely attractive method for synthesizing polymetallic clusters of paramagnetic transition metal ions. Here we give a brief overview of some of the complexes we have made so far, highlighting the enormous potential of the technique. (c) 2006 Elsevier Ltd. All rights reserved.