1-[(4-methyl-2-sulfido-1,3,2-dioxaphosphinian-2-yl)thio]pyrrolidine-2,5-dione | 1092388-17-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 恶嗪烷类
• 英文名称: 1-[(4-methyl-2-sulfido-1,3,2-dioxaphosphinian-2-yl)thio]pyrrolidine-2,5-dione
• CAS: 1092388-17-4
• 化学式: C₈H₁₂NO₄PS₂
• 分子量: 281.293
• InChiKey: UVVPMWOAEKKEFV-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  N-溴代丁二酰亚胺(NBS) 、 ammonium 1,3-O,O-butylene dithiophosphate 以 乙腈 为溶剂， 以70.41%的产率得到1-[(4-methyl-2-sulfido-1,3,2-dioxaphosphinian-2-yl)thio]pyrrolidine-2,5-dione
  参考文献：
  名称：

  Synthesis and Properties of N-Bromosuccinimide Derivatives of Ammonium Dialkyl/Alkylene Dithiophosphates

  摘要：

  Reactions of N-bromosuccinimide with ammonium salt of alkylene (dialkyl) dithiophosphates;[[GRAPHICS]NH4;G = -CMe2CMe2-CH2CMe2CH2-,CMe2CH2CHMe-, CH2CH2CHMe-; (RO)(2)PS2NH4; R=C2H5, n-C3H7, i-C3H7] in 1:1 molar ratio in refluxing benzene solution yields red / brown-colored sticky liquids. These newly synthesized complexes have been characterized by physicochemical and spectroscopic techniques (MW, IR, and NMR [H-1 and P-31]). The computational semi-empirical calculations (MOPAC6P/c) have also been studied for these complexes. On the basis of above studies, the formation of P-S-N chemical linkage has been established.

  DOI：

  10.1080/10426500701521597