iodo-1-(2'-aminophenyl)-2,6-diaza-6-methyl-9-amino-1-noneno copper(II) iodide | 131547-83-6

• 分子结构分类: 有机化合物 - 苯类化合物
• 英文名称: iodo-1-(2'-aminophenyl)-2,6-diaza-6-methyl-9-amino-1-noneno copper(II) iodide
• CAS: 131547-83-6
• 化学式: C₁₄H₂₄CuIN₄*I
• 分子量: 565.726
• InChiKey: MGRDCPUDCGTJBO-DPSBJRLESA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  copper(ll) sulfate pentahydrate 、 N,N-双(3-氨丙基)甲胺 、 2-氨基苯甲醛 在 BaI₂ 作用下， 以 甲醇 为溶剂， 以50%的产率得到iodo-1-(2'-aminophenyl)-2,6-diaza-6-methyl-9-amino-1-noneno copper(II) iodide
  参考文献：
  名称：

  Synthesis and crystal structure of iodo-1-(2′-aminophenyl)-2,6-diaza-6-methyl-9-amino-1-noneno copper(II) iodide

  摘要：

  Reaction of equimolar amounts of 2-aminobenzaldehyde and 3,3'-diamino-N-methyldipropylamine in methanol affords a novel 1:1 condensation product, abaMedpt, which has been isolated as the copper(II) complex, [Cu(abaMedpt)I]I. The crystal structure of the complex has been determined from single crystal diffractometer data and refined to a final R factor of 0.0353 with 2492 unique observations and 206 variables. The complex crystallizes in the monoclinic space group P2l/c (N-degrees-14) with a = 9.263(2), b = 18.189(3), c = 11.740(3) angstron, beta = 92.97(4)-degrees, Z = 4, D(c) = 1.902 g cm-3. The structure involves a five-coordinate square-pyramid CuN4I chromophore and an uncoordinated iodide anion. Nitrogen atoms constitute the basal plane, while the bonded iodine occupies the apical position. The structure contrasts with the more usual distorted trigonal-bipyramidal stereochemistries of CuN4I chromophores reported so far.

  DOI：

  10.1007/bf01158979