10,22-Dihydro-4,5-dioxo-4,5-secopyropheophorbide-a Methyl Ester | 138530-74-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 四吡咯及其衍生物
• 英文名称: 10,22-Dihydro-4,5-dioxo-4,5-secopyropheophorbide-a Methyl Ester
• CAS: 138530-74-2
• 化学式: C₃₄H₃₈N₄O₅
• 分子量: 582.7
• InChiKey: JVJMVCGTFNMFGF-SREIOGTFSA-N

反应信息

• 作为反应物：
  描述：

  10,22-Dihydro-4,5-dioxo-4,5-secopyropheophorbide-a Methyl Ester 在 氢氧化钾 作用下， 以 甲醇 、 水 为溶剂， 反应 5.0h， 以86%的产率得到10,22-Dihydro-4,5-dioxo-4,5-secopyropheophorbide-a
  参考文献：
  名称：

  A biomimetic partial synthesis of the red chlorophyll-a catabolite from Chlorella protothecoides.

  摘要：

  The red bilin derivative which is excreted in the culture medium by Chlorella protothecoides when this microalgae is grown in a medium rich in glucose but poor in nitrogen has been synthesized in two steps from one of the products of photo-oxidation of the Cd(II) complex of pyropheophorbide-a methyl ester. Under the same conditions, the Zn(II) complex of the latter is transformed into a blue bilin derivative which is an isomer of the foregoing chlorophyll-a catabolite.

  DOI：

  10.1016/s0040-4020(01)89871-9
• 作为产物：
  描述：

  在 sodium tetrahydroborate 作用下， 以 四氢呋喃 、 二氯甲烷 为溶剂， 以65%的产率得到10,22-Dihydro-4,5-dioxo-4,5-secopyropheophorbide-a Methyl Ester
  参考文献：
  名称：

  A biomimetic partial synthesis of the red chlorophyll-a catabolite from Chlorella protothecoides.

  摘要：

  The red bilin derivative which is excreted in the culture medium by Chlorella protothecoides when this microalgae is grown in a medium rich in glucose but poor in nitrogen has been synthesized in two steps from one of the products of photo-oxidation of the Cd(II) complex of pyropheophorbide-a methyl ester. Under the same conditions, the Zn(II) complex of the latter is transformed into a blue bilin derivative which is an isomer of the foregoing chlorophyll-a catabolite.

  DOI：

  10.1016/s0040-4020(01)89871-9