tetrabutylammonium salt of methyl-N-nitroamine | 63924-23-2

• 分子结构分类: 有机化合物 - 有机氧化合物 - 有机含氧阴离子化合物
• 英文名称: tetrabutylammonium salt of methyl-N-nitroamine
• 英文别名: tetrabutylammonium salt of methylnitramine
• CAS: 63924-23-2
• 化学式: CH₃N₂O₂*C₁₆H₃₆N
• 分子量: 317.516
• InChiKey: HCCMLHLZELOXNY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.08
• 重原子数：
  22.0
• 可旋转键数：
  12.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  61.49
• 氢给体数：
  0.0
• 氢受体数：
  3.0

反应信息

• 作为产物：
  描述：

  N-硝基甲胺 、 四丁基高氯酸铵 在 氢氧化钾 作用下， 以 甲醇 为溶剂， 生成 tetrabutylammonium salt of methyl-N-nitroamine
  参考文献：
  名称：

  Electrooxidation of primary nitramine anions on platinum in MeCN

  摘要：

  Oxidation of primary nitramine anions RNNO2-Bu4N+ (R = Me, Et, Pr-i, or methoxyfurazanyl) in 0.1 N Bu4NClO4 in MeCN on a Pt anode was studied by voltammetry and controlled potential electrolysis. It was found that the first stage of oxidation affords the corresponding radicals, which are further stabilized due to hydrogen abstraction from the medium. These radicals are also involved in other reactions, including those, which yield azo derivatives. The possibility of generation of nitrene species in these reactions is discussed.

  DOI：

  10.1007/bf02494746