[Pr((4-MeO)C6H3CH=NC6H3-2,6-iPr2)Cl]2(μ-4,4'-bipyridine) | 1384456-04-5

• 英文名称: [Pr((4-MeO)C6H3CH=NC6H3-2,6-iPr2)Cl]2(μ-4,4'-bipyridine)
• CAS: 1384456-04-5
• 化学式: C₅₀H₅₆Cl₂N₄O₂Pd₂
• 分子量: 1028.77
• InChiKey: QHDDDWMWEYCCJQ-VTKHPBHHSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  2,2'-联吡啶 、 [Pd((4-OMe)C6H3CH=NC6H3-2,6-i-Pr2)(μ-Cl)2 以 二氯甲烷 为溶剂， 以63%的产率得到[Pr((4-MeO)C6H3CH=NC6H3-2,6-iPr2)Cl]2(μ-4,4'-bipyridine)
  参考文献：
  名称：

  Synthesis, reactivity and characterization of mono-, bi- and tri-nuclear Schiff-base palladacycles with aromatic N-heterocycles

  摘要：

  Reactions of mu(2)-Chloro bridged cyclometallated Pd(II) complexes [Pd{(4-R) C6H3CH=NC6H3-2,6-i-Pr-2}(mu-Cl)] (2) (R = H, OMe) with aromatic N-heterocycles such as 1-methylimidazole, 4,4'-bipyridyl (bpy), 1,2-bis(4-pyridyl)-ethene (bpe), 2,5-bis(4-pyridyl)-1,3,4-thiadiazole (bpt) and 2,4,6-tris-(4-pyridyl)-1,3,5-triazine (tpt), generated mononuclear complexes [Pd{(4-R)C6H3CH=NC6H3-2,6-i-Pr-2}(L)(Cl)] (L = 1-methylimidazole, R = H, OMe), binuclear complexes [Pd{(4-R)C6H3CH=NC6H3-2,6-i-Pr-2}(Cl)](2)(mu-Y) (R = H, OMe; Y = bpy, bpe, bpt) and trinuclear complexes [Pd{(4-R) C6H3CH=NC6H3-2,6-i-Pr-2}(Cl)](3)(tpt) (R H, OMe). In contrast, the reaction of mu(2)-Chloro bridged cyclometallated Pd(II) complexes [Pd{(4-R) C6H3CH=NC6H3-2,6-i-Pr-2}(mu-Cl)](2) (R = H, OMe) with 2 equiv of AgNO3 and followed with bpy, bpe, bpt to produce binuclear cyclometallated Pd(II) nitrato complexes [Pd{(4-R) C6H3CH=NC6H3-2,6-i-Pr-2}(ONO2)](2)(mu-Y) (R H, OMe; Y bpy, bpe, bpt). Treatment of [Pd{(4-R)C6H3CH=NC6H3-2,6-i-Pr-2}(Cl)](3)(tpt) (R = H, OMe) with an excess AgNO3 produced trinuclear cyclometallated Pd(II) nitrato complexes [Pd{(4R)C6H3CH=NC6H3-2,6-i-Pr-2}(ONO2)](3)(tpt) (R H, OMe). All these complexes were fully characterized by FT-IR, NMR spectroscopy, elemental analysis and/or X-ray crystallography. (C) 2012 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2012.04.026