| 219135-86-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯
• CAS: 219135-86-1
• 化学式: C₂₂H₂₀N₄O₈V₂
• 分子量: 570.306
• InChiKey: JOWGUSRCFXLSKZ-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  吡啶 、 以 吡啶 、 水 为溶剂， 生成
  参考文献：
  名称：

  X-ray characterization of an unusual product obtained from [VO(Sal–Phe)(H2O)] in H2O\pyridine solutions

  摘要：

  A vanadium(V) dimer [{VO2(py)(2)}(2)(mu-C2O4)] 1, has been isolated from a solution of [VO(sal-Phe)(H2O)] 2 (sal-Phe = N-salicylidene-L-phenylalaninate) in H2O/pyridine. Its crystal and molecular structure has been determined by X-ray diffraction analysis, the oxalate acting as a symmetrical bis(chelating) bridge. Possible mechanisms for the formation of oxalate are briefly discussed. (C) 1998 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(98)00105-3