硝酸铵-15N2 | 43086-60-8

• 物质功能分类: 化学试剂 - 有机试剂 - 胺盐（铵盐）
• 分子结构分类: 无机化合物 - 均质非金属化合物 - 非金属氧阴离子化合物
• 中文名称: 硝酸铵-15N2
• 中文别名: 氮-15双标硝酸铵
• 英文名称: Ammonium nitrate-15N2
• CAS: 43086-60-8
• 化学式: HNO₃*H₃N
• 分子量: 82.03
• InChiKey: PRORZGWHZXZQMV-NPMJFZSBSA-N

物化性质

• 熔点：
  169 °C(lit.)
• 沸点：
  201 °C(lit.)
• 稳定性/保质期：

  遵照规定使用和储存，则不会分解。

计算性质

• 辛醇/水分配系数(LogP)：
  -0.19
• 重原子数：
  5
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  67
• 氢给体数：
  2
• 氢受体数：
  4

安全信息

• 危险类别码：
  R7,R36/37/38
• 危险品运输编号：
  UN 1942 5.1/PG 3
• 安全说明：
  S14,S26,S3,S36/37/39,S7

SDS

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SECTION 1: Identification of the substance/mixture and of the company/undertaking
Product identifiers
Product name : Ammonium nitrate-15N2
REACH No. : A registration number is not available for this substance as the substance
or its uses are exempted from registration, the annual tonnage does not
require a registration or the registration is envisaged for a later
registration deadline.
CAS-No. : 43086-60-8
Relevant identified uses of the substance or mixture and uses advised against
Identified uses : Laboratory chemicals, Manufacture of substances

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SECTION 2: Hazards identification
Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008
Oxidizing solids (Category 3), H272
Skin irritation (Category 2), H315
Eye irritation (Category 2), H319
Specific target organ toxicity - single exposure (Category 3), H335
For the full text of the H-Statements mentioned in this Section, see Section 16.
Classification according to EU Directives 67/548/EEC or 1999/45/EC
O, Xi Oxidising, Irritant R 8, R36/37/38
For the full text of the R-phrases mentioned in this Section, see Section 16.
Label elements
Labelling according Regulation (EC) No 1272/2008
Pictogram
Signal word Warning
Hazard statement(s)
H272 May intensify fire; oxidiser.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H335 May cause respiratory irritation.
Precautionary statement(s)
P220 Keep/Store away from clothing/ combustible materials.
P261 Avoid breathing dust.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
Supplemental Hazard none
Statements
Other hazards - none

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SECTION 3: Composition/information on ingredients
Substances
Chemical characterization : Isotopically labeled
Synonyms : Ammonium-15N nitrate-15N
Formula : H415N2O3
Molecular Weight : 82,03 g/mol
CAS-No. : 43086-60-8
Hazardous ingredients according to Regulation (EC) No 1272/2008
Component Classification Concentration
Ammonium nitrate-15N2
CAS-No. 43086-60-8 Ox. Sol. 3; Skin Irrit. 2; Eye <= 100 %
Irrit. 2; STOT SE 3; H272,
H315, H319, H335
Hazardous ingredients according to Directive 1999/45/EC
Component Classification Concentration
Ammonium nitrate-15N2
CAS-No. 43086-60-8 O, Xi, R 8 - R36/37/38 <= 100 %
For the full text of the H-Statements and R-Phrases mentioned in this Section, see Section 16

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SECTION 4: First aid measures
Description of first aid measures
General advice
Consult a physician. Show this safety data sheet to the doctor in attendance.
If inhaled
If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.
In case of skin contact
Wash off with soap and plenty of water. Consult a physician.
In case of eye contact
Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
If swallowed
Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.
Most important symptoms and effects, both acute and delayed
The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in
section 11
Indication of any immediate medical attention and special treatment needed
no data available

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SECTION 5: Firefighting measures
Extinguishing media
Suitable extinguishing media
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Special hazards arising from the substance or mixture
nitrogen oxides (NOx)
Advice for firefighters
Wear self contained breathing apparatus for fire fighting if necessary.
Further information
Use water spray to cool unopened containers.

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SECTION 6: Accidental release measures
Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. Avoid dust formation. Avoid breathing vapours, mist or gas. Ensure
adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust.
For personal protection see section 8.
Environmental precautions
Do not let product enter drains.
Methods and materials for containment and cleaning up
Sweep up and shovel. Contain spillage, and then collect with an electrically protected vacuum cleaner or
by wet-brushing and place in container for disposal according to local regulations (see section 13). Keep
in suitable, closed containers for disposal.
Reference to other sections
For disposal see section 13.

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SECTION 7: Handling and storage
Precautions for safe handling
Avoid contact with skin and eyes. Avoid formation of dust and aerosols.
Provide appropriate exhaust ventilation at places where dust is formed.Keep away from sources of ignition
- No smoking.Keep away from heat and sources of ignition.
For precautions see section 2.2.
Conditions for safe storage, including any incompatibilities
Store in cool place. Keep container tightly closed in a dry and well-ventilated place.
Store under inert gas. hygroscopic
Specific end use(s)
Apart from the uses mentioned in section 1.2 no other specific uses are stipulated

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SECTION 8: Exposure controls/personal protection
Control parameters
Components with workplace control parameters
Exposure controls
Appropriate engineering controls
Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and
at the end of workday.
Personal protective equipment
Eye/face protection
Safety glasses with side-shields conforming to EN166 Use equipment for eye protection tested
and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).
Skin protection
Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique
(without touching glove's outer surface) to avoid skin contact with this product. Dispose of
contaminated gloves after use in accordance with applicable laws and good laboratory practices.
Wash and dry hands.
The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and
the standard EN 374 derived from it.
Body Protection
impervious clothing, The type of protective equipment must be selected according to the
concentration and amount of the dangerous substance at the specific workplace.
Respiratory protection
Where risk assessment shows air-purifying respirators are appropriate use a full-face particle
respirator type N100 (US) or type P3 (EN 143) respirator cartridges as a backup to engineering
controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use
respirators and components tested and approved under appropriate government standards such
as NIOSH (US) or CEN (EU).
Control of environmental exposure
Do not let product enter drains.

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SECTION 9: Physical and chemical properties
Information on basic physical and chemical properties
a) Appearance Form: solid
b) Odour no data available
c) Odour Threshold no data available
d) pH no data available
e) Melting point/freezing Melting point/range: 169 °C - lit.
point
f) Initial boiling point and 210 °C - lit.
boiling range
g) Flash point no data available
h) Evapouration rate no data available
i) Flammability (solid, gas) no data available
j) Upper/lower no data available
flammability or
explosive limits
k) Vapour pressure no data available
l) Vapour density no data available
m) Relative density no data available
n) Water solubility no data available
o) Partition coefficient: n- no data available
octanol/water
p) Auto-ignition no data available
temperature
q) Decomposition no data available
temperature
r) Viscosity no data available
s) Explosive properties no data available
t) Oxidizing properties The substance or mixture is classified as oxidizing with the category 3.
Other safety information
no data available

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SECTION 10: Stability and reactivity
Reactivity
no data available
Chemical stability
Stable under recommended storage conditions.
Possibility of hazardous reactions
no data available
Conditions to avoid
no data available
Incompatible materials
Reducing agents, Powdered metals, Strong acids
Hazardous decomposition products
In the event of fire: see section 5

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SECTION 11: Toxicological information
Information on toxicological effects
Acute toxicity
LD50 Oral - rat - 2.217 mg/kg
Inhalation: Irritating to respiratory system.
Skin corrosion/irritation
no data available
Serious eye damage/eye irritation
no data available
Respiratory or skin sensitisation
no data available
Germ cell mutagenicity
no data available
Carcinogenicity
IARC: No component of this product present at levels greater than or equal to 0.1% is identified as
probable, possible or confirmed human carcinogen by IARC.
Reproductive toxicity
no data available
Specific target organ toxicity - single exposure
Inhalation - May cause respiratory irritation.
Specific target organ toxicity - repeated exposure
no data available
Aspiration hazard
no data available
Additional Information
RTECS: Not available
prolonged or repeated exposure can cause:, Gastrointestinal disturbance, Blood disorders, To the best of
our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

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SECTION 12: Ecological information
Toxicity
no data available
Persistence and degradability
no data available
Bioaccumulative potential
no data available
Mobility in soil
no data available
Results of PBT and vPvB assessment
PBT/vPvB assessment not available as chemical safety assessment not required/not conducted
Other adverse effects
no data available

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SECTION 13: Disposal considerations
Waste treatment methods
Product
Burn in a chemical incinerator equipped with an afterburner and scrubber but exert extra care in igniting
as this material is highly flammable. Offer surplus and non-recyclable solutions to a licensed disposal
company.
Contaminated packaging
Dispose of as unused product.

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SECTION 14: Transport information
UN number
ADR/RID: 1942 IMDG: 1942 IATA: 1942
UN proper shipping name
ADR/RID: AMMONIUM NITRATE
IMDG: AMMONIUM NITRATE
IATA: Ammonium nitrate
Transport hazard class(es)
ADR/RID: 5.1 IMDG: 5.1 IATA: 5.1
Packaging group
ADR/RID: III IMDG: III IATA: III
Environmental hazards
ADR/RID: no IMDG Marine pollutant: no IATA: no
Special precautions for user
no data available

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SECTION 15: Regulatory information
This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006.
Safety, health and environmental regulations/legislation specific for the substance or mixture
no data available
Chemical Safety Assessment
For this product a chemical safety assessment was not carried out

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SECTION 16: Other information
Full text of H-Statements referred to under sections 2 and 3.
Eye Irrit. Eye irritation
H272 May intensify fire; oxidiser.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H335 May cause respiratory irritation.
Ox. Sol. Oxidizing solids
Skin Irrit. Skin irritation
STOT SE Specific target organ toxicity - single exposure
Full text of R-phrases referred to under sections 2 and 3
O Oxidising
Xi Irritant
R8 Contact with combustible material may cause fire.
R36/37/38 Irritating to eyes, respiratory system and skin.
Further information
Copyright 2014 Co. LLC. License granted to make unlimited paper copies for internal use
only.
The above information is believed to be correct but does not purport to be all inclusive and shall be
used only as a guide. The information in this document is based on the present state of our knowledge
and is applicable to the product with regard to appropriate safety precautions. It does not represent any
guarantee of the properties of the product. Corporation and its Affiliates shall not be held
liable for any damage resulting from handling or from contact with the above product. See
and/or the reverse side of invoice or packing slip for additional terms and conditions of sale.

反应信息

• 作为反应物：
  描述：

  硝酸铵-15N2 反应 72.0h， 生成 亚硝氧化物-15N2
  参考文献：
  名称：

  一氧化二氮铑（I）钳形配合物。

  摘要：

  报道了两种明确定义的一氧化二氮（N2 O）铑（I）配合物的合成。这些通常难以捉摸的加合物在固态下稳定，并在环境温度下在溶液中持续存在，可通过15 N NMR和IR光谱以及单晶X射线衍射对结构进行全面研究。这些方法证明了N2 O通过末端氮原子以线性方式进行配位，并辅以计算能分解分析，从而进一步了解了Rh-N2 O相互作用的性质。

  DOI：

  10.1002/anie.201908333
• 作为产物：
  描述：

  氮气-15N2 、 水 、 氧气 在 nitrogen-vacancy pothole-rich few-layer g-C₃N₄ 作用下， 反应 3.0h， 生成 硝酸铵-15N2
  参考文献：
  名称：

  易于合成的富氮空缺孔少层gC 3 N 4，用于光催化固氮为硝酸盐和氨水

  摘要：

  与传统的哈伯-博世（Haber-Bosch）工艺相比，在水中使用光催化剂固氮既节能又环保。人工固氮大多产生的氨（NH 4 +）和很少制成硝酸盐（NO 3 - ）。该同时产生NH一种光催化反应4 +和NO 3 -少数报道物。在这项工作中，通过冰水浴超声和大量gC 3 N 4的快速二次烧结，简单地合成了富氮空孔的少层gC 3 N 4（PF-gC 3 N 4）。PF-GC 3Ñ 4可同时实现光催化氮还原反应（NRR）和氮氧化反应（NOR），以产生NH 4 +（82.14微摩尔大号-1 ħ -1克猫-1）和NO 3 -（109.96微摩尔大号-1 ħ - 1 g cat -1），使用空气作为氮源，在水中不添加任何牺牲剂，PF-gC 3 N 4的总固氮产物收率比本体gC 3 N 4高1.66倍。但是在存在空穴牺牲剂和N 2的情况下作为氮源，使用PF-gC 3 N 4固氮几乎为NRR，产生NH 4 +（315

  DOI：

  10.1016/j.jallcom.2021.159298
• 作为试剂：
  描述：

  尿素-15N2 在 silica bead 硝酸铵-15N2 作用下， 以 melt 为溶剂， 反应 1.25h， 以6.68 g的产率得到
  参考文献：
  名称：

  硝基胍的结构：硝基胺还是硝基亚胺？来自 15N 标记样品和 15N 自旋耦合常数的新 NMR 证据

  摘要：

  硝基胍的结构通过在 DMSO-d6 和 DMF 溶液中应用 15N、1H 和 13C NMR 光谱以及固态 15N CP/MAS NMR 对完全 15N 标记的样品进行研究。这些光谱证实了近年来其他研究提出的硝基亚胺结构，并且不支持常用的硝基胺结构或与硝基胺的互变异构平衡。报告了指定结构中 1H 和 13C 核的有用 15N 自旋耦合常数。

  DOI：

  10.1002/mrc.1260250311