Yb[PPh2]2(N-methylimidazole)4 | 166821-09-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Yb[PPh2]2(N-methylimidazole)4
• CAS: 166821-09-6
• 化学式: C₄₀H₄₄N₈P₂Yb
• 分子量: 871.83
• InChiKey: VBCNYAHQMPKOHC-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  N-甲基咪唑 、 Yb[PPh2]2(tetrahydrofuran)4 以 四氢呋喃 为溶剂， 以>99的产率得到Yb[PPh2]2(N-methylimidazole)4
  参考文献：
  名称：

  Divalent Lanthanide Chemistry: Three Synthetic Routes to Samarium(II) and Ytterbium(II) Bis(phosphido) Species Including the Structural Characterization of Yb[PPh2]2(thf)4 and Sm[PPh2]2(N-MeIm)4

  摘要：

  As part of a general investigation of low-valent lanthanide phosphido chemistry, the reactions of LnI(2)(thf)(2), LnI(3)(thf)(3), and Ln[N(SiMe(3))(2)](2)(thf)(2) (Ln = Yb, Sm) with KPPh(2) and Ph(2)PH in tetrahydrofuran have been examined. Two different types of lanthanide(II) phosphido complexes of the general formula Ln[PPh(2)](2)(L)(4) with either thf or N-methylimidazole as donor ligands L are reported. The molecular structures show the hexacoordinate lanthanide atoms in slightly distorted octahedral environments with two phosphido ligands in trans positions and slightly pyramidal environments around the phosphorus atoms.

  DOI：

  10.1021/ic00122a003