Co tetrapyrazinoporphyrazine | 26603-06-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶吡嗪类
• 英文名称: Co tetrapyrazinoporphyrazine
• 英文别名: tetrapyrazinoporphyrazine, cobalt complex；tetrapyrazinoporphyrazine cobalt complex；cobalt(II) tetrapyrazinoporphyrazine；cobalt tetrapyrazinoporphyrazine；CoPTpz；Co(tetrapyrazinoporphyrazine)
• CAS: 26603-06-5
• 化学式: C₂₄H₈CoN₁₆
• 分子量: 579.428
• InChiKey: MNNNEVSSDHNLGA-UHFFFAOYSA-N

物化性质

• 熔点：
  >300 °C

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  Co tetrapyrazinoporphyrazine 在 氯化亚砜 、 lithium tetrachloroaluminate 作用下， 生成 CoPTpz*SOCl2
  参考文献：
  名称：

  Effect of N atoms in the backbone of metal phthalocyanine derivatives on their catalytic activity to lithium battery

  摘要：

  Metal phthalocyanine (MPc, M = Mn2+, Fe2+, Co2+, Ni2+ and Cu2+). metal tetrapyridinoporphyrazine, and metal tetrapyrazinoporphyrazine are synthesized by microwave reaction and characterized by elemental analyzer, IR spectroscopy and UV-vis spectroscopy. The catalytic activity of MPc derivatives to Li/SOCl2 battery is evaluated by the relative discharge energy of the battery whose electrolyte contains the compounds. The discharge energy of Li/SOCl2 battery catalyzed by MPc is approximately 0-61% higher than that of Li/SOCl2 battery in the absence of compounds, depending on the central metal ion. To the same central metal ion, the discharge energy of Li/SOCl2 battery catalyzed by MTAP is approximately 60% higher than that by MPc. The discharge energy of Li/SOCl2 battery in which SOCl2 contains MPTpz is approximately 17-19% higher than that of the battery in the absence Of compounds, and almost independent of central metal ions. It shows a correlation existing between the Structure and the catalytic active sites of MPc derivatives. The double active site model is proposed to interpret the results. (C) 2009 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molcata.2009.11.014
• 作为产物：
  描述：

  2,3-吡嗪二羧酸 、 尿素 在 ammonium dimolybdate 、 cobalt(II) chloride hexahydrate 作用下， 反应 0.27h， 以54%的产率得到Co tetrapyrazinoporphyrazine
  参考文献：
  名称：

  Effect of N atoms in the backbone of metal phthalocyanine derivatives on their catalytic activity to lithium battery

  摘要：

  Metal phthalocyanine (MPc, M = Mn2+, Fe2+, Co2+, Ni2+ and Cu2+). metal tetrapyridinoporphyrazine, and metal tetrapyrazinoporphyrazine are synthesized by microwave reaction and characterized by elemental analyzer, IR spectroscopy and UV-vis spectroscopy. The catalytic activity of MPc derivatives to Li/SOCl2 battery is evaluated by the relative discharge energy of the battery whose electrolyte contains the compounds. The discharge energy of Li/SOCl2 battery catalyzed by MPc is approximately 0-61% higher than that of Li/SOCl2 battery in the absence of compounds, depending on the central metal ion. To the same central metal ion, the discharge energy of Li/SOCl2 battery catalyzed by MTAP is approximately 60% higher than that by MPc. The discharge energy of Li/SOCl2 battery in which SOCl2 contains MPTpz is approximately 17-19% higher than that of the battery in the absence Of compounds, and almost independent of central metal ions. It shows a correlation existing between the Structure and the catalytic active sites of MPc derivatives. The double active site model is proposed to interpret the results. (C) 2009 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molcata.2009.11.014
• 作为试剂：
  描述：

  氯化亚砜 在 Co tetrapyrazinoporphyrazine LiAlCl₄ 作用下， 以 水 为溶剂， 生成 二氧化硫 、 sulfur
  参考文献：
  名称：

  Effect of N atoms in the backbone of metal phthalocyanine derivatives on their catalytic activity to lithium battery

  摘要：

  Metal phthalocyanine (MPc, M = Mn2+, Fe2+, Co2+, Ni2+ and Cu2+). metal tetrapyridinoporphyrazine, and metal tetrapyrazinoporphyrazine are synthesized by microwave reaction and characterized by elemental analyzer, IR spectroscopy and UV-vis spectroscopy. The catalytic activity of MPc derivatives to Li/SOCl2 battery is evaluated by the relative discharge energy of the battery whose electrolyte contains the compounds. The discharge energy of Li/SOCl2 battery catalyzed by MPc is approximately 0-61% higher than that of Li/SOCl2 battery in the absence of compounds, depending on the central metal ion. To the same central metal ion, the discharge energy of Li/SOCl2 battery catalyzed by MTAP is approximately 60% higher than that by MPc. The discharge energy of Li/SOCl2 battery in which SOCl2 contains MPTpz is approximately 17-19% higher than that of the battery in the absence Of compounds, and almost independent of central metal ions. It shows a correlation existing between the Structure and the catalytic active sites of MPc derivatives. The double active site model is proposed to interpret the results. (C) 2009 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molcata.2009.11.014