methyldiiodo(trimethylstiban)antimony | 141872-84-6

• 分子结构分类: 有机化合物 - 有机盐 - 有机金属盐
• 英文名称: methyldiiodo(trimethylstiban)antimony
• CAS: 141872-84-6
• 化学式: CH₃I₂Sb*C₃H₉Sb
• 分子量: 557.448
• InChiKey: FIYRHAXEUKQXLH-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  3.35
• 重原子数：
  8.0
• 可旋转键数：
  1.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为产物：
  描述：

  Dimethyljodstibin 以 petroleum ether 为溶剂， 以30%的产率得到methyldiiodo(trimethylstiban)antimony
  参考文献：
  名称：

  Strukturen von [Me4Sb]2[MeSbI4]MeSbI2, und [Me4Sb]I. Darstellung von Me3Sb · MeSbI2 und farbwechsel bei Me4Sb2 · Me2SbBr

  摘要：

  The crystal structures of the complex [Me4Sb]2[MeSbI4] (1) and its precursors MeSbI2 (2) and [Me4Sb]I (3) are reported. In 1 there are tetrahedral cations and square pyramidal anions with Sb-I distances of 290-320 pm. The structure of 2 contains MeSbI2 molecules. They associate via iodine bridges to form linear chains with alternating short and long Sb-I distances. The coordination around antimony is distorted tetragonal pyramidal. The tetrahedral coordination of the ions in 3 results in the formation of a wurtzite type structure with antimony-iodine distances of 406 and 435 pm. The novel adducts Me3Sb.MeSbI2 (4) and Me2SbSbMe2.Me2SbBr (5) are formed by reaction of the components. They decompose easily with formation of antimony(V) compounds. Crystals of 5 are yellow but become reversibly black on cooling.

  DOI：

  10.1016/0022-328x(92)83203-t